Production of certified reference materials for the sports doping control of the REV-ERB agonist SR9009.

SR9009 certified reference materials human metabolites purity assignment synthesis

Journal

Drug testing and analysis
ISSN: 1942-7611
Titre abrégé: Drug Test Anal
Pays: England
ID NLM: 101483449

Informations de publication

Date de publication:
Feb 2019
Historique:
received: 18 06 2018
revised: 16 07 2018
accepted: 10 08 2018
pubmed: 22 8 2018
medline: 2 7 2019
entrez: 22 8 2018
Statut: ppublish

Résumé

Two human metabolites of the REV-ERB agonist SR9009, identified by researchers with an interest in sports doping control, have been synthesized and assessed for purity. The synthesis employed was a modification of published procedures for the parent SR9009, careful attention to the purification of intermediates and the final product ensuring materials of the highest purity were available for certification. For each candidate material impurities of related structure were identified and quantified as a relative mass fraction using high performance liquid chromatography-ultraviolet (HPLC-UV) detection and proton nuclear magnetic resonance (

Identifiants

pubmed: 30129998
doi: 10.1002/dta.2485
doi:

Substances chimiques

Pyrrolidines 0
SR9009 0
Thiophenes 0

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

257-266

Subventions

Organisme : Partnership for Clean Competition
ID : 2015 230000 NMI R215 Davies

Informations de copyright

© 2018 Commonwealth of Australia. Drug Testing and Analysis © 2018 John Wiley & Sons, Ltd.

Auteurs

Stephen R Davies (SR)

Chemical Reference Materials, National Measurement Institute, Riverside Corporate Park, North Ryde, Sydney, NSW, 2113, Australia.

Benjamin K H Chan (BKH)

Chemical Reference Materials, National Measurement Institute, Riverside Corporate Park, North Ryde, Sydney, NSW, 2113, Australia.

Michael Moawad (M)

Chemical Reference Materials, National Measurement Institute, Riverside Corporate Park, North Ryde, Sydney, NSW, 2113, Australia.

Taylor R Garrett (TR)

Chemical Reference Materials, National Measurement Institute, Riverside Corporate Park, North Ryde, Sydney, NSW, 2113, Australia.

Lance Brooker (L)

Australian Sports Drug Testing Laboratory, National Measurement Institute, Riverside Corporate Park, North Ryde, Sydney, NSW, 2113, Australia.

Rima Chakrabarty (R)

Australian Sports Drug Testing Laboratory, National Measurement Institute, Riverside Corporate Park, North Ryde, Sydney, NSW, 2113, Australia.

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Classifications MeSH