The reHISS Three-Range Exchange Functional with an Optimal Variation of Hartree-Fock and Its Use in the reHISSB-D Density Functional Theory Method.

DFT HISS functional kinetics noncovalent interaction range separation screened exchange solid-state property thermochemistry

Journal

Journal of computational chemistry
ISSN: 1096-987X
Titre abrégé: J Comput Chem
Pays: United States
ID NLM: 9878362

Informations de publication

Date de publication:
05 Jan 2019
Historique:
received: 01 03 2018
revised: 01 06 2018
accepted: 01 06 2018
pubmed: 19 9 2018
medline: 19 9 2018
entrez: 19 9 2018
Statut: ppublish

Résumé

In the present study, we have reparametrized the HISS exchange functional. The new "reHISS" exchange provides a balance between short- and mid-range Hartree-Fock exchange (HFX) and a large total HFX coverage, with a fast convergence to zero HFX in the long range. The five parameters in this functional (according to equations 3 and 4 in the main text) are c

Identifiants

pubmed: 30226643
doi: 10.1002/jcc.25383
doi:

Types de publication

Journal Article

Langues

eng

Pagination

29-38

Subventions

Organisme : Institute for Molecular Science
ID : 23225001
Organisme : Japan Society for the Promotion of Science
ID : 16H07074
Organisme : Japan Society for the Promotion of Science
ID : 16K05676
Organisme : Japan Society for the Promotion of Science
ID : 23225001

Informations de copyright

© 2018 Wiley Periodicals, Inc.

Auteurs

Bun Chan (B)

Graduate School of Engineering, Nagasaki University, Bunkyo 1-14, Nagasaki-shi, Nagasaki, 852-8521, Japan.

Yukio Kawashima (Y)

RIKEN Advanced Institute for Computational Science, 7-1-26 Minatojima-minami-machi, Chuo-ku, Kobe, Hyogo, 650-0047, Japan.

Kimihiko Hirao (K)

RIKEN Advanced Institute for Computational Science, 7-1-26 Minatojima-minami-machi, Chuo-ku, Kobe, Hyogo, 650-0047, Japan.

Classifications MeSH