Designing Dimeric Lanthanide(III)-Containing Ionic liquids.
Dimer
Ionic Liquids
Lanthanides
Magnetic Properties
Materials Chemistry
Journal
Angewandte Chemie (International ed. in English)
ISSN: 1521-3773
Titre abrégé: Angew Chem Int Ed Engl
Pays: Germany
ID NLM: 0370543
Informations de publication
Date de publication:
06 Feb 2023
06 Feb 2023
Historique:
received:
13
08
2022
pubmed:
25
9
2018
medline:
25
9
2018
entrez:
25
9
2018
Statut:
ppublish
Résumé
Herein, we report on the preparation of liquid dimeric lanthanide(III)-containing compounds. Starting from the design of dimeric solids, we demonstrate that by tuning of anion and cation structures we can lower the melting points below room temperature, whilst maintaining the dimeric structure. Magnetic measurements could establish the spin-spin interactions of the neighboring lanthanide(III) ions in the liquid state at low temperatures, and matched the interactions of the analogous crystalline solid compounds.
Identifiants
pubmed: 30246909
doi: 10.1002/anie.201809334
doi:
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Pagination
e201809334Subventions
Organisme : Engineering and Physical Sciences Research Council
ID : S3802ASA
Organisme : Royal Society
ID : RG130739
Informations de copyright
© 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.
Références
J.-C. G. Bünzli, C. Piguet, Chem. Soc. Rev. 2005, 34, 1048.
S.-F. Tang, A. Babai, A.-V. Mudring, Angew. Chem. Int. Ed. 2008, 47, 7631-7634;
Angew. Chem. 2008, 120, 7743-7756;
B. Mallick, B. Balke, C. Felser, A.-V. Mudring, Angew. Chem. Int. Ed. 2008, 47, 7635-7638;
Angew. Chem. 2008, 120, 7747-7750;
D. Prodius, V. Smetana, S. Steinberg, M. Wilk-Kozubek, Y. Mudynk, V. K. Pecharsky, A.-V. Mudring, Materials Horizon 2017, 4, 217-222;
E. T. Spielberg, E. Edengeißer, B. Mallick, M. Havenith, A.-V. Mudring, Chem. Eur. J. 2014, 20, 5338-5345.
J.-P. Costes, F. Dahan, A. Dupuis, S. Lagrave, J.-P. Laurent, Inorg. Chem. 1998, 37, 153-155.
D.-Z. Liao, Y.-Z. Tong, Q.-L. Wang, A.-P. Zhang, Y. Ma, S.-P. Yan, G.-M. Yang, P. Cheng, Inorg. Chem. Commun. 2013, 32, 32-36.
S. Ren, S. L. Ma, G. F. Xu, B. Gu, Y. Ma, Q. L. Wang, D. Z. Liao, Inorg. Chem. Commun. 2011, 14, 1124-1127.
A. Ouchi, Y. Suzuki, Y. Ohki, Y. Koizumi, Coord. Chem. Rev. 1988, 92, 29-43.
D. N. Woodruff, R. E. P. Winpenny, R. A. Layfield, Chem. Rev. 2013, 113, 5110-5148.
P. Wasserscheid, T. Welton, Ionic Liquids in Synthesis, Wiley-VCH, Weinheim, 2002.
P. Wasserscheid, W. Keim, Angew. Chem. Int. Ed. 2000, 39, 3772-3789;
Angew. Chem. 2000, 112, 3926-3945.
T. Welton, Chem. Rev. 1999, 99, 2071-2084.
M. Freemantle, An Introduction to Ionic Liquids, RSC Pub, London, 2010.
A. E. Visser, J. D. Holbrey, R. D. Rogers, Chem. Commun. 2001, 2484-2485.
Y. Yoshida, I. Fujii, K. Muroi, A. Otsuka, G. Saito, M. Takahashi, T. Yoko, Synth. Met. 2005, 153, 421-424.
S. Hayashi, H.-O. Hamaguchi, Chem. Lett. 2004, 33, 1590-1591.
E. Santos, J. Albo, A. Irabien, RSC Adv. 2014, 4, 40008-40018.
R. E. Del Sesto, T. M. Mccleskey, A. K. Burrell, G. A. Baker, J. D. Thompson, B. L. Scott, J. S. Wilkes, P. Williams, Chem. Commun. 2008, 447-449.
S. Pitula, A. V. Mudring, Chem. Eur. J. 2010, 16, 3355-3365.
T. Peppel, M. Köckerling, M. Geppert-Rybczyńska, R. V. Ralys, J. K. Lehmann, S. P. Verevkin, A. Heintz, Angew. Chem. Int. Ed. 2010, 49, 7116-7119;
Angew. Chem. 2010, 122, 7270-7274.
I. De Pedro, D. P. Rojas, J. Albo, P. Luis, A. Irabien, J. Us, A. Blanco, J. Rodríguez Fernández, J. Phys. Condens. Matter 2010, 22, 296006-296004.
P. Nockemann, B. Thijs, N. Postelmans, K. Van Hecke, L. Van Meervelt, K. Binnemans, J. Am. Chem. Soc. 2006, 128, 13658-13659.
D. Prodius, F. Macaev, Y. Lan, G. Novitchi, S. Pogrebnoi, E. Stingaci, V. Mereacre, C. E. Anson, A. K. Powell, Chem. Commun. 2013, 49, 9215-9217.
J. Alvarez-Vicente, S. Dandil, D. Banerjee, H. Q. N. Gunaratne, S. Gray, S. Felton, G. Srinivasan, A. M. Kaczmarek, R. Van Deun, P. Nockemann, J. Phys. Chem. B 2016, 120, 5301-5311.
T. C. Monson, T. E. Stevens, J. L. Leger, J. L. Manson, K. S. Lovejoy, A. L. Newsham, R. E. Del Sesto, Chem. Commun. 2017, 53, 11682-11685.
P. Nockemann, B. Thijs, K. Lunstroot, T. N. Parac-Voet, C. Görller-Walrand, K. Binnemans, K. Van Hecke, L. Van Meervelt, S. Nikitenko, J. Daniels, et al., Chem. Eur. J. 2009, 15, 1449-1461.
G. B. Deacon, R. J. Phillips, Coord. Chem. Rev. 1980, 33, 227.
J. M. D. Coey, Magnetism and Magnetic Materials, Cambridge University Press, Cambridge 2010.
Y. Peng, V. Mereacre, C. Anson, A. Powell, Inorganics 2016, 4, 2.
L. Liu, Y. Li, S. X. Deng, Y. P. Zhang, Inorg. Chim. Acta 2017, 457, 1-6.
P. Comba, M. Großhauser, R. Klingeler, C. Koo, Y. Lan, D. Müller, J. Park, A. Powell, M. J. Riley, H. Wadepohl, Inorg. Chem. 2015, 54, 11247-11258.
C. J. O'Connor in Progress in Inorganic Chemistry (Ed.: S. J. Lippard), Wiley, Hoboken, 2007, pp. 203-282.
I. A. Kahwa, J. Selbin, C. J. O'Connor, J. W. Foise, G. L. McPherson, Inorg. Chim. Acta 1988, 148, 265-272.
B. Li, W. Gu, L.-Z. Zhang, J. Qu, Z.-P. Ma, X. Liu, D.-Z. Liao, Inorg. Chem. 2006, 45, 10425-10427.
N. Xu, W. Shi, D. Z. Liao, S. P. Yan, P. Cheng, Inorg. Chem. 2008, 47, 8748-8756.
N. Xu, C. Wang, W. Shi, S. P. Yan, P. Cheng, D. Z. Liao, Eur. J. Inorg. Chem. 2011, 2387-2393.
J.-K. Tang, Q.-L. Wang, S.-F. Si, D.-Z. Liao, Z.-H. Jiang, S.-P. Yan, P. Cheng, Inorg. Chim. Acta 2004, 325-330.