C-I-Selective Cross-Coupling Enabled by a Cationic Palladium Trimer.
C−C bond formation
chemoselectivity
cross-coupling
density functional calculations
palladium trimers
Journal
Angewandte Chemie (International ed. in English)
ISSN: 1521-3773
Titre abrégé: Angew Chem Int Ed Engl
Pays: Germany
ID NLM: 0370543
Informations de publication
Date de publication:
02 Jan 2019
02 Jan 2019
Historique:
received:
04
10
2018
pubmed:
2
11
2018
medline:
2
11
2018
entrez:
2
11
2018
Statut:
ppublish
Résumé
While there is a growing interest in harnessing synergistic effects of more than one metal in catalysis, relatively little is known beyond bimetallic systems. This report describes the straightforward access to an air-stable Pd trimer and presents unambiguous reactivity data of its privileged capability to differentiate C-I over C-Br bonds in C-C bond formations (arylation and alkylation) of polyhalogenated arenes, which typical Pd
Identifiants
pubmed: 30381881
doi: 10.1002/anie.201811380
doi:
Types de publication
Journal Article
Langues
eng
Pagination
211-215Subventions
Organisme : H2020 European Research Council
ID : ERC-637993
Informations de copyright
© 2019 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.