Triple-Shelled Manganese-Cobalt Oxide Hollow Dodecahedra with Highly Enhanced Performance for Rechargeable Alkaline Batteries.

manganese-cobalt oxide multi-shelled structures rechargeable alkaline batteries zeolitic imidazolate frameworks (ZIFs)

Journal

Angewandte Chemie (International ed. in English)
ISSN: 1521-3773
Titre abrégé: Angew Chem Int Ed Engl
Pays: Germany
ID NLM: 0370543

Informations de publication

Date de publication:
21 Jan 2019
Historique:
received: 11 10 2018
pubmed: 15 11 2018
medline: 15 11 2018
entrez: 15 11 2018
Statut: ppublish

Résumé

Precisely carving of multi-shelled manganese-cobalt oxide hollow dodecahedra (Co/Mn-HD) with shell number up to three is achieved by a controlled calcination of the Mn-doped zeolitic imidazolate framework ZIF-67 precursor (Co/Mn-ZIF). The unique multi-shelled and polycrystalline structure not only provides a very large electrochemically active surface area (EASA), but also enhances the structural stability of the material. The residual C and N in the final structures might aid stability and increase their conductivity. When used in alkaline rechargeable battery, the triple-shelled Co/Mn-HD exhibits high electrochemical performance, reversible capacity (331.94 mAh g

Identifiants

DOI: 10.1002/anie.201811683 PMID: 30426625
pubmed: 30426625
doi: 10.1002/anie.201811683
doi:

Types de publication

Journal Article

Langues

eng

Pagination

996-1001

Subventions

Organisme : National Natural Science Foundation of China
ID : 51472025
Organisme : National Natural Science Foundation of China
ID : 21671016
Organisme : National Natural Science Foundation of China
ID : 51872024
Organisme : National Natural Science Foundation of China
ID : 21590795
Organisme : National Natural Science Foundation of China
ID : 21820102002
Organisme : Foundation for CAS Interdisciplinary Innovation Team, the Scientific Instrument Developing Project of the Chinese Academy of Sciences
ID : YZ201623
Organisme : Queensland-Chinese Academy of Sciences Collaborative Science Fund
ID : 122111KYSB20170001

Informations de copyright

© 2019 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

Auteurs

Chuangwei Jiao (C)

School of Metallurgical and Ecological Engineering, University of Science and Technology Beijing, No. 30, Xueyuan Road, Haidian District, Beijing, 100083, China.
Institute of Process Engineering, Chinese Academy of Sciences, 1 North 2nd Street, Zhongguancun, Beijing, 100190, China.
ORCID: 0000-0001-5838-9221

Zumin Wang (Z)

School of Metallurgical and Ecological Engineering, University of Science and Technology Beijing, No. 30, Xueyuan Road, Haidian District, Beijing, 100083, China.
Institute of Process Engineering, Chinese Academy of Sciences, 1 North 2nd Street, Zhongguancun, Beijing, 100190, China.
ORCID: 0000-0002-0732-787X

Xiaoxian Zhao (X)

School of Metallurgical and Ecological Engineering, University of Science and Technology Beijing, No. 30, Xueyuan Road, Haidian District, Beijing, 100083, China.
Institute of Process Engineering, Chinese Academy of Sciences, 1 North 2nd Street, Zhongguancun, Beijing, 100190, China.

Huan Wang (H)

School of Metallurgical and Ecological Engineering, University of Science and Technology Beijing, No. 30, Xueyuan Road, Haidian District, Beijing, 100083, China.
Institute of Process Engineering, Chinese Academy of Sciences, 1 North 2nd Street, Zhongguancun, Beijing, 100190, China.

Jing Wang (J)

School of Metallurgical and Ecological Engineering, University of Science and Technology Beijing, No. 30, Xueyuan Road, Haidian District, Beijing, 100083, China.
Institute of Process Engineering, Chinese Academy of Sciences, 1 North 2nd Street, Zhongguancun, Beijing, 100190, China.

Ranbo Yu (R)

School of Metallurgical and Ecological Engineering, University of Science and Technology Beijing, No. 30, Xueyuan Road, Haidian District, Beijing, 100083, China.
ORCID: 0000-0003-3028-190X

Dan Wang (D)

Institute of Process Engineering, Chinese Academy of Sciences, 1 North 2nd Street, Zhongguancun, Beijing, 100190, China.

Classifications MeSH