New antiradical capacity assay with the use potentiometric method.
AAPH
Peroxyl radical
Potentiometry
Total antiradical capacity
Journal
Analytica chimica acta
ISSN: 1873-4324
Titre abrégé: Anal Chim Acta
Pays: Netherlands
ID NLM: 0370534
Informations de publication
Date de publication:
10 Jan 2019
10 Jan 2019
Historique:
received:
21
05
2018
revised:
16
08
2018
accepted:
13
09
2018
entrez:
29
11
2018
pubmed:
30
11
2018
medline:
28
3
2019
Statut:
ppublish
Résumé
For the first time, the dependence of a redox potential change during a reaction of peroxyl radical generation and their interaction with antioxidants was studied. A regular change of a potential is due to oxidation of an antioxidant by initiating peroxyl radicals accompanied by an electron transfer. An original direct method for determining induction periods, inhibition coefficients and an antiradical capacity using the potentiometric method is proposed. Using the proposed approach the induction periods and the inhibition coefficients of various OH, NH, SH containing antioxidants were determined. The antiradical capacity of a herbal extract was studied. A high degree of correlation with a DPPH assay was obtained. RSD results obtained using the proposed approach do not exceed 7%.
Identifiants
pubmed: 30482304
pii: S0003-2670(18)31096-1
doi: 10.1016/j.aca.2018.09.025
pii:
doi:
Substances chimiques
Peroxides
0
perhydroxyl radical
3170-83-0
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Pagination
69-76Informations de copyright
Copyright © 2018 Elsevier B.V. All rights reserved.