Methylene Group Transfer in Carbonyl Compounds Discovered in silico and Detected Experimentally.

ab initio calculations carbonyl compounds density functional calculations heated capillary mass spectrometry

Journal

Chemphyschem : a European journal of chemical physics and physical chemistry
ISSN: 1439-7641
Titre abrégé: Chemphyschem
Pays: Germany
ID NLM: 100954211

Informations de publication

Date de publication:
04 02 2019
Historique:
received: 09 10 2018
revised: 04 12 2018
pubmed: 14 12 2018
medline: 14 12 2018
entrez: 8 12 2018
Statut: ppublish

Résumé

A previously unknown transformation of aldehydes, ketones, and carboxylic acid derivatives leads to the formation of substituted oxiranes, aziridines, and azirines as shown by DFT and MP2 computations. Formations of 2,2-dimethyloxirane-d

Identifiants

pubmed: 30523648
doi: 10.1002/cphc.201800945
doi:

Types de publication

Journal Article Research Support, Non-U.S. Gov't

Langues

eng

Pagination

361-365

Subventions

Organisme : Russian Science Foundation
ID : 18-79-10127
Pays : International

Informations de copyright

© 2019 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

Auteurs

Ilya D Gridnev (ID)

Graduate School of Science, Tohoku University Aramaki Aza Aoba 6-3, Aoba-ku, Sendai, 9808578, Japan.

Alexander Zherebker (A)

Center of Life Science, Skolkovo institute of Science and technology, 3 Nobelya str., Moscow, 121205, Russia.

Yury Kostyukevich (Y)

Center of Life Science, Skolkovo institute of Science and technology, 3 Nobelya str., Moscow, 121205, Russia.

Eugene Nikolaev (E)

Center of Life Science, Skolkovo institute of Science and technology, 3 Nobelya str., Moscow, 121205, Russia.

Classifications MeSH