Enantioselective Acyl Migration Reactions of Furanyl Carbonates with Chiral DMAP Derivatives.
DMAP derivative
acyl migration
enantioselectivity
organocatalysis
quaternary stereogenic center
Journal
Chemistry (Weinheim an der Bergstrasse, Germany)
ISSN: 1521-3765
Titre abrégé: Chemistry
Pays: Germany
ID NLM: 9513783
Informations de publication
Date de publication:
11 Feb 2019
11 Feb 2019
Historique:
received:
05
12
2018
pubmed:
12
12
2018
medline:
12
12
2018
entrez:
12
12
2018
Statut:
ppublish
Résumé
An efficient enantioselective acyl migration reaction of furanyl carbonates was developed to construct all-carbon quaternary stereogenic centers. In some cases, the reactions required only 0.05 mol % (minimum 500 ppm) of catalyst and showed a high turnover frequency value (TOF; 3640 h
Identifiants
pubmed: 30536459
doi: 10.1002/chem.201806050
doi:
Types de publication
Journal Article
Langues
eng
Pagination
2208-2212Subventions
Organisme : Japan Society for the Promotion of Science
ID : 17K17903
Informations de copyright
© 2019 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.