Titanium Carbene Complexes Stabilized by Alkali Metal Amides.

Wittig reaction alkali metals alkylidenes carbenes titanium

Journal

Angewandte Chemie (International ed. in English)
ISSN: 1521-3773
Titre abrégé: Angew Chem Int Ed Engl
Pays: Germany
ID NLM: 0370543

Informations de publication

Date de publication:
04 Feb 2019
Historique:
received: 01 11 2018
pubmed: 15 12 2018
medline: 15 12 2018
entrez: 15 12 2018
Statut: ppublish

Résumé

Facile α-H elimination from tetrakis(trimethylsilylmethyl)titanium precursors to give adducts of (alkylidene)bis(alkyl)titanium complexes is induced by light alkali metal amides of the NNNN-type macrocyclic anionic ligand Me

Identifiants

pubmed: 30548105
doi: 10.1002/anie.201812579
doi:

Types de publication

Journal Article

Langues

eng

Pagination

1833-1837

Subventions

Organisme : Deutsche Forschungsgemeinschaft
ID : GRK1628

Informations de copyright

© 2019 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

Auteurs

Hassan Osseili (H)

Institute of Inorganic Chemistry, RWTH Aachen University, Landoltweg 1, 52056, Aachen, Germany.

Khai-Nghi Truong (KN)

Institute of Inorganic Chemistry, RWTH Aachen University, Landoltweg 1, 52056, Aachen, Germany.

Thomas P Spaniol (TP)

Institute of Inorganic Chemistry, RWTH Aachen University, Landoltweg 1, 52056, Aachen, Germany.

Laurent Maron (L)

CNRS, INSA, UPS, UMR 5215, LPCNO, Université de Toulouse, 135 avenue de Rangueil, 31077, Toulouse, France.

Ulli Englert (U)

Institute of Inorganic Chemistry, RWTH Aachen University, Landoltweg 1, 52056, Aachen, Germany.

Jun Okuda (J)

Institute of Inorganic Chemistry, RWTH Aachen University, Landoltweg 1, 52056, Aachen, Germany.

Classifications MeSH