A Three-Membered Cyclic Phosphasilene.
coordination chemistry
heavier multiple bonds
phosphorus
silicon
small rings
Journal
Angewandte Chemie (International ed. in English)
ISSN: 1521-3773
Titre abrégé: Angew Chem Int Ed Engl
Pays: Germany
ID NLM: 0370543
Informations de publication
Date de publication:
11 Feb 2019
11 Feb 2019
Historique:
received:
17
10
2018
revised:
29
11
2018
pubmed:
15
12
2018
medline:
15
12
2018
entrez:
15
12
2018
Statut:
ppublish
Résumé
Small unsaturated phosphacycles are versatile reagents owing to their strain and the added functionality of the double bond and the phosphorus lone pair. Herein we report the synthesis and isolation of the smallest possible cyclic phosphasilene as a stable adduct with an N-heterocyclic carbene (NHC). First reactivity studies show a) that the PSi
Identifiants
pubmed: 30548984
doi: 10.1002/anie.201811944
doi:
Types de publication
Journal Article
Langues
eng
Pagination
1939-1944Subventions
Organisme : Deutsche Forschungsgemeinschaft
ID : SCHE 906/4-1 and 4-2
Organisme : European Cooperation in Science and Technology
ID : CM1302
Organisme : Deutsche Forschungsgemeinschaft
ID : SCHE 906/4-2
Informations de copyright
© 2019 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.