Conductive Fused Porphyrin Tapes on Sensitive Substrates by a Chemical Vapor Deposition Approach.
chemical vapor deposition
oxidative coupling
polymerization
porphyrins
thin films
Journal
Angewandte Chemie (International ed. in English)
ISSN: 1521-3773
Titre abrégé: Angew Chem Int Ed Engl
Pays: Germany
ID NLM: 0370543
Informations de publication
Date de publication:
11 Feb 2019
11 Feb 2019
Historique:
received:
10
12
2018
pubmed:
18
12
2018
medline:
18
12
2018
entrez:
18
12
2018
Statut:
ppublish
Résumé
Oxidative polymerization of nickel(II) 5,15-diphenyl porphyrin and nickel(II) 5,15-bis(di-3,5-tert-butylphenyl) porphyrin by oxidative chemical vapor deposition (oCVD) yields multiply fused porphyrin oligomers in thin film form. The oCVD technique enables one-step formation, deposition, and p-doping of conjugated poly(porphyrins) coatings without solvents or post-treatments. The decisive reactions and side reactions during the oCVD process are shown by high-resolution mass spectrometry. Owing to the highly conjugated structure of the fused tapes, the thin films exhibit an electrical conductivity of 3.6×10
Identifiants
pubmed: 30556943
doi: 10.1002/anie.201814034
pmc: PMC6582438
doi:
Types de publication
Journal Article
Langues
eng
Pagination
2103-2108Subventions
Organisme : Fonds National de la Recherche Luxembourg
ID : C15/MS/10340560/POLYPORH/Boscher
Informations de copyright
© 2019 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA.
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