Reactions between N-Heterocyclic Carbene and Lutetium-Metallofullerenes: High Regioselectivity Directed by Electronic Effect in Addition to Steric Hindrance.
Journal
The Journal of organic chemistry
ISSN: 1520-6904
Titre abrégé: J Org Chem
Pays: United States
ID NLM: 2985193R
Informations de publication
Date de publication:
18 Jan 2019
18 Jan 2019
Historique:
pubmed:
1
1
2019
medline:
1
1
2019
entrez:
1
1
2019
Statut:
ppublish
Résumé
The Lewis acid-base pairing reaction between strained N-heterocyclic carbene (NHC) and endohedral metallofullerenes (EMFs) is an efficient strategy to obtain stable derivatives in a highly regioselective manner. Herein, we report an in-depth study on the reactions between 3-dimesityl-1 H-imidazol-3-ium-2-ide (1) and three different EMFs, namely, Lu
Identifiants
pubmed: 30596235
doi: 10.1021/acs.joc.8b02423
doi:
Types de publication
Journal Article
Langues
eng