Redox titration on foldable paper-based analytical devices for the visual determination of alcohol content in whiskey samples.

Alcoholic beverages Crime scene Food control Forensic chemistry Paper microfluidics Point-of-need

Journal

Talanta
ISSN: 1873-3573
Titre abrégé: Talanta
Pays: Netherlands
ID NLM: 2984816R

Informations de publication

Date de publication:
01 Mar 2019
Historique:
received: 01 08 2018
revised: 09 10 2018
accepted: 09 10 2018
entrez: 6 1 2019
pubmed: 6 1 2019
medline: 6 1 2019
Statut: ppublish

Résumé

This report describes the development of foldable paper-based analytical devices (PADs) to perform redox titrations. Paper devices were designed to contain three spot tests, which were wax printed and folded to create a three-layer structured platform and to promote the sample transport based on vertical flow. The proposed devices were explored for the visual determination of the alcoholic content in whiskey samples. For this purpose, a classical permanganometry reaction was employed to allow the indirect determination of ethanol based on the required amount of oxalic acid to react with the excess of permanganate in acidic medium. The endpoint of the redox titrations performed in different alcoholic concentrations was measured and revealed a good linear behavior for the ethanol concentration range between 0% and 50% (R

Identifiants

pubmed: 30609544
pii: S0039-9140(18)31070-1
doi: 10.1016/j.talanta.2018.10.036
pii:
doi:

Types de publication

Journal Article

Langues

eng

Pagination

363-369

Informations de copyright

Copyright © 2018 Elsevier B.V. All rights reserved.

Auteurs

Sandro A Nogueira (SA)

Instituto de Química, Universidade Federal de Goiás, 74690-900 Goiânia, GO, Brazil.

Adriano D Lemes (AD)

Laboratório Nacional Agropecuário, 74674-025 Goiânia, GO, Brazil.

Adriana C Chagas (AC)

Laboratório Nacional Agropecuário, 74674-025 Goiânia, GO, Brazil.

Maurício L Vieira (ML)

Instituto Nacional de Criminalística, Departamento de Policia Federal, 70610-200 Brasília, DF, Brazil.

Márcio Talhavini (M)

Instituto Nacional de Criminalística, Departamento de Policia Federal, 70610-200 Brasília, DF, Brazil.

Pedro A O Morais (PAO)

Instituto de Química, Universidade Federal de Goiás, 74690-900 Goiânia, GO, Brazil.

Wendell K T Coltro (WKT)

Instituto de Química, Universidade Federal de Goiás, 74690-900 Goiânia, GO, Brazil; Instituto Nacional de Ciência e Tecnologia de Bioanalítica, 13084-971 Campinas, SP, Brazil. Electronic address: wendell@ufg.br.

Classifications MeSH