Strong Duschinsky Mixing Induced Breakdown of Kasha's Rule in an Organic Phosphor.
Journal
The journal of physical chemistry letters
ISSN: 1948-7185
Titre abrégé: J Phys Chem Lett
Pays: United States
ID NLM: 101526034
Informations de publication
Date de publication:
07 Feb 2019
07 Feb 2019
Historique:
pubmed:
9
1
2019
medline:
9
1
2019
entrez:
9
1
2019
Statut:
ppublish
Résumé
We present the novel observation that Duschinsky mixings can lead to the breakdown of Kasha's rule in a white light phosphor molecule, dibenzo[ b, d]thiophen-2-yl (4-chlorophenyl)methanone. Our theoretical analyses show the energy gap between the T
Identifiants
pubmed: 30620609
doi: 10.1021/acs.jpclett.8b03624
doi:
Types de publication
Journal Article
Langues
eng