Diverse outcomes of CO
Journal
Chemical communications (Cambridge, England)
ISSN: 1364-548X
Titre abrégé: Chem Commun (Camb)
Pays: England
ID NLM: 9610838
Informations de publication
Date de publication:
29 Jan 2019
29 Jan 2019
Historique:
pubmed:
16
1
2019
medline:
16
1
2019
entrez:
16
1
2019
Statut:
ppublish
Résumé
Fixation of CO2 by lithium amides derived from pyrrole and diisopropylamine generates a lithium carbamate polymer and dodecamer respectively. Moving to lithium-sodium hexamethyldisilazide produces a more complicated, intriguing reaction, where unusually the bimetallic composition is maintained in the product but its composition contains both carbamato and anhydride functionalities.
Types de publication
Journal Article
Langues
eng