Glycerol confined in zeolitic imidazolate frameworks: The temperature-dependent cooperativity length scale of glassy freezing.

Journal

The Journal of chemical physics
ISSN: 1089-7690
Titre abrégé: J Chem Phys
Pays: United States
ID NLM: 0375360

Informations de publication

Date de publication:
14 Jan 2019
Historique:
entrez: 17 1 2019
pubmed: 17 1 2019
medline: 17 1 2019
Statut: ppublish

Résumé

In the present work, we employ broadband dielectric spectroscopy to study the molecular dynamics of the prototypical glass former glycerol confined in two microporous zeolitic imidazolate frameworks (ZIF-8 and ZIF-11) with well-defined pore diameters of 1.16 and 1.46 nm, respectively. The spectra reveal information on the modified

Identifiants

DOI: 10.1063/1.5080334 PMID: 30646699
pubmed: 30646699
doi: 10.1063/1.5080334
doi:

Types de publication

Journal Article

Langues

eng

Pagination

024504

Auteurs

M Uhl (M)

Experimental Physics V, Center for Electronic Correlations and Magnetism, University of Augsburg, 86135 Augsburg, Germany.
ORCID: 0000000188969120

J K H Fischer (JKH)

Experimental Physics V, Center for Electronic Correlations and Magnetism, University of Augsburg, 86135 Augsburg, Germany.
ORCID: 0000000181290713

P Sippel (P)

Experimental Physics V, Center for Electronic Correlations and Magnetism, University of Augsburg, 86135 Augsburg, Germany.

H Bunzen (H)

Chair of Solid State and Materials Chemistry, Institute of Physics, University of Augsburg, 86135 Augsburg, Germany.
ORCID: 0000000318240291

P Lunkenheimer (P)

Experimental Physics V, Center for Electronic Correlations and Magnetism, University of Augsburg, 86135 Augsburg, Germany.
ORCID: 0000000245251394

D Volkmer (D)

Chair of Solid State and Materials Chemistry, Institute of Physics, University of Augsburg, 86135 Augsburg, Germany.
ORCID: 0000000281052157

A Loidl (A)

Experimental Physics V, Center for Electronic Correlations and Magnetism, University of Augsburg, 86135 Augsburg, Germany.
ORCID: 0000000255790746

Classifications MeSH