Tailored Palladate Tunable Aryl Alkyl Ionic Liquids (TAAILs).
anionic complexes
imidazolium salts
ionic liquids
palladates
palladium
Journal
Chemistry (Weinheim an der Bergstrasse, Germany)
ISSN: 1521-3765
Titre abrégé: Chemistry
Pays: Germany
ID NLM: 9513783
Informations de publication
Date de publication:
18 Feb 2019
18 Feb 2019
Historique:
received:
30
08
2018
pubmed:
17
1
2019
medline:
17
1
2019
entrez:
17
1
2019
Statut:
ppublish
Résumé
We present a new class of tunable aryl alkyl ionic liquids (TAAILs) containing different palladate counter ions. Solid-state structures for representative compounds have been obtained. Their properties are presented in comparison to those of newly synthesized and reported palladate ionic liquids with conventional counter ions. It was found that the aryl substitution pattern and the type of anion have a profound influence on the melting point. The speciation of the different anions in solution has been rationalized by DFT calculations.
Identifiants
pubmed: 30650210
doi: 10.1002/chem.201804431
doi:
Types de publication
Journal Article
Langues
eng
Pagination
2527-2537Subventions
Organisme : Studienstiftung des Deutschen Volkes
Informations de copyright
© 2019 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.