Unifying the Hydrogen Evolution and Oxidation Reactions Kinetics in Base by Identifying the Catalytic Roles of Hydroxyl-Water-Cation Adducts.


Journal

Journal of the American Chemical Society
ISSN: 1520-5126
Titre abrégé: J Am Chem Soc
Pays: United States
ID NLM: 7503056

Informations de publication

Date de publication:
20 02 2019
Historique:
pubmed: 24 1 2019
medline: 24 1 2019
entrez: 24 1 2019
Statut: ppublish

Résumé

Despite the fundamental and practical significance of the hydrogen evolution and oxidation reactions (HER/HOR), their kinetics in base remain unclear. Herein, we show that the alkaline HER/HOR kinetics can be unified by the catalytic roles of the adsorbed hydroxyl (OH

Identifiants

pubmed: 30673227
doi: 10.1021/jacs.8b13228
doi:

Types de publication

Journal Article Research Support, U.S. Gov't, Non-P.H.S.

Langues

eng

Sous-ensembles de citation

IM

Pagination

3232-3239

Auteurs

Ershuai Liu (E)

Department of Chemistry and Chemical Biology , Northeastern University , Boston , Massachusetts 02115 , United States.

Jingkun Li (J)

Department of Chemistry and Chemical Biology , Northeastern University , Boston , Massachusetts 02115 , United States.

Li Jiao (L)

Department of Chemical Engineering , Northeastern University , Boston , Massachusetts 02115 , United States.

Huong Thi Thanh Doan (HTT)

Department of Chemistry and Chemical Biology , Northeastern University , Boston , Massachusetts 02115 , United States.

Zeyan Liu (Z)

Department of Materials Science and Engineering , University of California , Los Angeles , California 90095 , United States.

Zipeng Zhao (Z)

Department of Materials Science and Engineering , University of California , Los Angeles , California 90095 , United States.

Yu Huang (Y)

Department of Materials Science and Engineering , University of California , Los Angeles , California 90095 , United States.
California NanoSystems Institute (CNSI) , University of California , Los Angeles , California 90095 , United States.

K M Abraham (KM)

Department of Chemistry and Chemical Biology , Northeastern University , Boston , Massachusetts 02115 , United States.

Sanjeev Mukerjee (S)

Department of Chemistry and Chemical Biology , Northeastern University , Boston , Massachusetts 02115 , United States.

Qingying Jia (Q)

Department of Chemistry and Chemical Biology , Northeastern University , Boston , Massachusetts 02115 , United States.

Classifications MeSH