Lattice Opening upon Bulk Reductive Covalent Functionalization of Black Phosphorus.
31P NMR spectroscopy
Raman spectroscopy
black phosphorus
covalent functionalization
reductive route
Journal
Angewandte Chemie (International ed. in English)
ISSN: 1521-3773
Titre abrégé: Angew Chem Int Ed Engl
Pays: Germany
ID NLM: 0370543
Informations de publication
Date de publication:
16 Apr 2019
16 Apr 2019
Historique:
received:
28
09
2018
revised:
18
01
2019
pubmed:
25
1
2019
medline:
25
1
2019
entrez:
25
1
2019
Statut:
ppublish
Résumé
The chemical bulk reductive covalent functionalization of thin-layer black phosphorus (BP) using BP intercalation compounds has been developed. Through effective reductive activation, covalent functionalization of the charged BP by reaction with organic alkyl halides is achieved. Functionalization was extensively demonstrated by means of several spectroscopic techniques and DFT calculations; the products showed higher functionalization degrees than those obtained by neutral routes.
Identifiants
pubmed: 30675972
doi: 10.1002/anie.201811181
pmc: PMC7318246
doi:
Types de publication
Journal Article
Langues
eng
Pagination
5763-5768Subventions
Organisme : FP7 Ideas: European Research Council
ID : ERC Advanced Grant 742145 B-PhosphoChem
Organisme : FP7 Ideas: European Research Council
ID : grant agreement No. 604391 Graphene Flagship
Organisme : European Research Council
ID : ERC Starting Grant 2D-PnictoChem 804110
Pays : International
Organisme : Deutsche Forschungsgemeinschaft
ID : SFB 953 "Synthetic Carbon Allotropes"
Organisme : Deutsche Forschungsgemeinschaft
ID : FLAG-ERA AB694/2-1
Organisme : "la Caixa" Foundation
ID : Junior Leader Fellowship
Organisme : Generalitat Valenciana
ID : SEJI/2018/034 grant
Organisme : Friedrich-Alexander-Universität Erlangen-Nürnberg
ID : Emerging Talents Initiative grant #WS16-17_Nat_04
Organisme : Alexander von Humboldt-Stiftung
ID : Postdoctoral Fellowship
Organisme : Spanish MINECO
ID : Project CTQ2017-86735-P
Organisme : Ministerio de Economía y Competitividad
ID : Excellence Unit María de Maeztu (MDM-2015-0538)
Organisme : Free State of Bavaria
ID : Research Network "Solar Technologies go Hybrid"
Informations de copyright
© 2019 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.
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