Dynamics of frequency-swept nuclear spin optical pumping in powdered diamond at low magnetic fields.

Landau−Zener crossing diamond powder hyperpolarization nitrogen vacancy centers optical spin pumping

Journal

Proceedings of the National Academy of Sciences of the United States of America
ISSN: 1091-6490
Titre abrégé: Proc Natl Acad Sci U S A
Pays: United States
ID NLM: 7505876

Informations de publication

Date de publication:
12 02 2019
Historique:
pubmed: 27 1 2019
medline: 27 1 2019
entrez: 26 1 2019
Statut: ppublish

Résumé

A broad effort is underway to improve the sensitivity of NMR through the use of dynamic nuclear polarization. Nitrogen vacancy (NV) centers in diamond offer an appealing platform because these paramagnetic defects can be optically polarized efficiently at room temperature. However, work thus far has been mainly limited to single crystals, because most polarization transfer protocols are sensitive to misalignment between the NV and magnetic field axes. Here we study the spin dynamics of NV-

Identifiants

pubmed: 30679282
pii: 1811994116
doi: 10.1073/pnas.1811994116
pmc: PMC6377465
doi:

Types de publication

Journal Article Research Support, U.S. Gov't, Non-P.H.S. Research Support, Non-U.S. Gov't

Langues

eng

Pagination

2512-2520

Déclaration de conflit d'intérêts

Conflict of interest: Some of the authors have pending patent applications related to the present study: “Orientation-independent, room-temperature, hyperpolarization of diamond nano- and micro-particles,” A.P., A.A., R.N., X. Lv, C.A.M., provisional application US 62/581,238 filed by University of California, Berkeley, November 3, 2017; “Method for hyperpolarizing nuclear spins at arbitrary magnetic fields,” C.A.M., D.P., A. Laraoui, nonprovisional application Serial No. US 14/961,974, filed by Research Foundation-City University of New York (RF-CUNY), December 8, 2015, priority date December 8, 2014, US Patent Publication No. US-2016-0161583-A1 (June 9, 2016); and “Method and apparatus for polarizing nuclear and electronic spins,” C.A.M., nonprovisional application, Serial No. US 14/781,127, International Application No. PCT/US14/33175, filed by Research Foundation-CUNY, April 7, 2014, priority date April 5, 2013, US Patent Publication No. 2016-0054402-A1 (February 25, 2016), International Publication No. WO 2014/165845 A1 (October 9, 2014).

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Auteurs

Pablo R Zangara (PR)

Department of Physics, City College of New York, City University of New York, New York, NY 10031.

Siddharth Dhomkar (S)

Department of Physics, City College of New York, City University of New York, New York, NY 10031.

Ashok Ajoy (A)

Department of Chemistry, University of California, Berkeley, CA 94720.
Materials Science Division, Lawrence Berkeley National Laboratory, Berkeley, CA 94720.

Kristina Liu (K)

Department of Chemistry, University of California, Berkeley, CA 94720.
Materials Science Division, Lawrence Berkeley National Laboratory, Berkeley, CA 94720.

Raffi Nazaryan (R)

Department of Chemistry, University of California, Berkeley, CA 94720.
Materials Science Division, Lawrence Berkeley National Laboratory, Berkeley, CA 94720.

Daniela Pagliero (D)

Department of Physics, City College of New York, City University of New York, New York, NY 10031.

Dieter Suter (D)

Fakultät Physik, Technische Universität Dortmund, D-44221 Dortmund, Germany.

Jeffrey A Reimer (JA)

Materials Science Division, Lawrence Berkeley National Laboratory, Berkeley, CA 94720.
Department of Chemical and Biomolecular Engineering, University of California, Berkeley, CA 94720.

Alexander Pines (A)

Department of Chemistry, University of California, Berkeley, CA 94720.
Materials Science Division, Lawrence Berkeley National Laboratory, Berkeley, CA 94720.

Carlos A Meriles (CA)

Department of Physics, City College of New York, City University of New York, New York, NY 10031; cmeriles@ccny.cuny.edu.
Graduate Center, City University of New York, New York, NY 10016.

Classifications MeSH