Isotope fractionation due to aqueous phase diffusion - What do diffusion models and experiments tell? - A review.
Journal
Chemosphere
ISSN: 1879-1298
Titre abrégé: Chemosphere
Pays: England
ID NLM: 0320657
Informations de publication
Date de publication:
Mar 2019
Mar 2019
Historique:
received:
20
08
2018
revised:
30
11
2018
accepted:
05
12
2018
entrez:
27
1
2019
pubmed:
27
1
2019
medline:
23
2
2019
Statut:
ppublish
Résumé
For the interpretation of stable isotope ratio trends in saturated geochemical systems, the magnitude of aqueous phase diffusion-induced isotope fractionation needs to be known. This study reviews how five diffusion models (Fick, Maxwell-Stefan, Einstein, Langevin, Mode-Coupling Theory Analysis (MCTA) of diffusion) predict isotope fractionation due to aqueous phase diffusion and compares them with experimental results. The reviewed diffusion models were not consistent regarding the prediction of the mass (m) dependency of the aqueous phase diffusion coefficient (D). The predictions range from a square root power law (D ∝ m
Identifiants
pubmed: 30682760
pii: S0045-6535(18)32360-9
doi: 10.1016/j.chemosphere.2018.12.038
pii:
doi:
Substances chimiques
Isotopes
0
Solutions
0
Water
059QF0KO0R
Types de publication
Journal Article
Review
Langues
eng
Sous-ensembles de citation
IM
Pagination
1032-1043Informations de copyright
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