Terminal hydridozinc cation.
Journal
Chemical communications (Cambridge, England)
ISSN: 1364-548X
Titre abrégé: Chem Commun (Camb)
Pays: England
ID NLM: 9610838
Informations de publication
Date de publication:
12 Feb 2019
12 Feb 2019
Historique:
pubmed:
29
1
2019
medline:
29
1
2019
entrez:
29
1
2019
Statut:
ppublish
Résumé
A thermally stable terminal hydridozinc cation has been isolated. The nucleophilicity of the hydride ligand is demonstrated by inserting carbon dioxide, carbodiimide and benzophenone across the Zn-H bond in a facile manner. Preliminary studies on catalytic hydrosilylation using PhSiH3 indicate that the hydridozinc cation in the presence of BPh3 can selectively reduce CO2 to PhSi(OCHO)3.
Types de publication
Journal Article
Langues
eng