Vinyl Triflimides-A Case of Assisted Vinyl Cation Formation.
alkynes
enzyme-mimicking synthesis
hydroaminosulfonation
triflimides
vinyl cations
Journal
Angewandte Chemie (International ed. in English)
ISSN: 1521-3773
Titre abrégé: Angew Chem Int Ed Engl
Pays: Germany
ID NLM: 0370543
Informations de publication
Date de publication:
01 Apr 2019
01 Apr 2019
Historique:
received:
21
09
2018
revised:
28
11
2018
pubmed:
30
1
2019
medline:
30
1
2019
entrez:
30
1
2019
Statut:
ppublish
Résumé
A new concept for selectivity control in carbocation-driven reactions has been identified which allows for the chemo-, regio-, and stereoselective addition of nucleophiles to alkynes-assisted vinyl cation formation-enabled by a Li
Identifiants
pubmed: 30694004
doi: 10.1002/anie.201810916
doi:
Types de publication
Journal Article
Langues
eng
Pagination
5119-5123Informations de copyright
© 2019 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.