Palladium-Catalyzed Enantioselective Alkenylation of Sulfenate Anions.

Journal

Organic letters
ISSN: 1523-7052
Titre abrégé: Org Lett
Pays: United States
ID NLM: 100890393

Informations de publication

Date de publication:
15 02 2019
Historique:
pubmed: 30 1 2019
medline: 30 1 2019
entrez: 30 1 2019
Statut: ppublish

Résumé

A novel approach to synthesize enantio-enriched alkenyl/aryl sulfoxides is achieved by using CsF to generate sulfenate anions and conducting the catalytic enantioselective alkenylation with [Pd(allyl)Cl]

Identifiants

DOI: 10.1021/acs.orglett.8b03943 PMID: 30694063
pubmed: 30694063
doi: 10.1021/acs.orglett.8b03943
doi:

Types de publication

Journal Article Research Support, U.S. Gov't, Non-P.H.S.

Langues

eng

Pagination

960-964

Auteurs

Chen Wu (C)

Roy and Diana Vagelos Laboratories, Department of Chemistry , University of Pennsylvania , 231 South 34th Street , Philadelphia , Pennsylvania 19104-6323 , United States.
ORCID: 0000-0001-7427-1661

Simon Berritt (S)

Roy and Diana Vagelos Laboratories, Department of Chemistry , University of Pennsylvania , 231 South 34th Street , Philadelphia , Pennsylvania 19104-6323 , United States.

Xiaoxia Liang (X)

Roy and Diana Vagelos Laboratories, Department of Chemistry , University of Pennsylvania , 231 South 34th Street , Philadelphia , Pennsylvania 19104-6323 , United States.
Natural Medicine Research Center, College of Veterinary Medicine , Sichuan Agricultural University , Chengdu 611130 , People's Republic of China.
ORCID: 0000-0001-5002-5327

Patrick J Walsh (PJ)

Roy and Diana Vagelos Laboratories, Department of Chemistry , University of Pennsylvania , 231 South 34th Street , Philadelphia , Pennsylvania 19104-6323 , United States.
ORCID: 0000-0001-8392-4150

Classifications MeSH