Energetics and Escape of Interchain-Delocalized Ion Pairs in Nonpolar Media.

charge separation conjugated polymers delocalization ion pair microwave conductivity

Journal

Advanced materials (Deerfield Beach, Fla.)
ISSN: 1521-4095
Titre abrégé: Adv Mater
Pays: Germany
ID NLM: 9885358

Informations de publication

Date de publication:
Mar 2019
Historique:
received: 23 10 2018
revised: 04 01 2019
pubmed: 31 1 2019
medline: 31 1 2019
entrez: 31 1 2019
Statut: ppublish

Résumé

The electron acceptor F4TCNQ p-dopes aggregates "nanowires" of poly(3-hexylthiophene) in nonpolar solvents but does not dope unaggregated chains. The standard free energy change for the charge transfer to form an ion pair is ΔG°

Identifiants

pubmed: 30697829
doi: 10.1002/adma.201806863
doi:

Types de publication

Journal Article

Langues

eng

Pagination

e1806863

Subventions

Organisme : Geosciences & Biosciences
ID : DE-SC0012704

Informations de copyright

© 2019 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Auteurs

John H Burke (JH)

Department of Chemistry, University of Vermont, Burlington, VT, 05405, USA.

Matthew J Bird (MJ)

Chemistry Division, Brookhaven National Laboratory, Upton, NY, 11973, USA.

Classifications MeSH