Phosphahelicenes: From Chiroptical and Photophysical Properties to OLED Applications.
OLEDs
circular dichroism
luminescence
phosphahelicenes
quantum chemical calculations
Journal
Chemistry (Weinheim an der Bergstrasse, Germany)
ISSN: 1521-3765
Titre abrégé: Chemistry
Pays: Germany
ID NLM: 9513783
Informations de publication
Date de publication:
05 Apr 2019
05 Apr 2019
Historique:
received:
11
12
2018
revised:
04
02
2019
pubmed:
5
2
2019
medline:
5
2
2019
entrez:
5
2
2019
Statut:
ppublish
Résumé
Herein, the experimental physicochemical and chiroptical properties of a series of phosphahelicenes are reported, focusing on their UV/Vis absorption, luminescence, electronic circular dichroism, optical rotations, and circularly polarized luminescence. Furthermore, detailed analysis of absorption and ECD spectra performed with the help of quantum-chemical calculations allowed us to highlight general features of these helicenic phosphines. Finally, due to well-suited electrochemical properties and thermal stability, the systems were successfully used as emitters in organic light-emitting diodes.
Identifiants
pubmed: 30714652
doi: 10.1002/chem.201806140
pmc: PMC7063663
mid: NIHMS1567133
doi:
Types de publication
Journal Article
Langues
eng
Pagination
5303-5310Subventions
Organisme : NIGMS NIH HHS
ID : SC3 GM089589
Pays : United States
Organisme : National Institute of Health
ID : GM089589-08
Organisme : Agence Nationale de la Recherche
ID : ANR-15-CE29-0012-03
Informations de copyright
© 2019 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.
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