Convenient Access to Chiral Cyclobutanes with Three Contiguous Stereocenters from Verbenone by Directed C(sp

8-aminoquinoline C(sp3)−H functionalization cyclobutanes palladium verbenone

Journal

Chemistry (Weinheim an der Bergstrasse, Germany)
ISSN: 1521-3765
Titre abrégé: Chemistry
Pays: Germany
ID NLM: 9513783

Informations de publication

Date de publication:
05 Apr 2019
Historique:
received: 27 12 2018
pubmed: 5 2 2019
medline: 5 2 2019
entrez: 5 2 2019
Statut: ppublish

Résumé

This work demonstrates how a series of complex, chiral cyclobutane derivatives can be accessed in four steps from the terpene verbenone through the application of a directed C-H functionalization approach. The developed synthetic route involved an 8-aminoquinoline-directed C(sp

Identifiants

pubmed: 30716181
doi: 10.1002/chem.201806416
doi:

Types de publication

Journal Article

Langues

eng

Pagination

5154-5157

Subventions

Organisme : Wenner-Gren Foundation
ID : FT2018-0002

Informations de copyright

© 2019 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

Auteurs

Alexander J Schmitz (AJ)

Department of Organic Chemistry, Arrhenius Laboratory, Stockholm University, 10691, Stockholm, Sweden.
Institut für Organische Chemie, RWTH Aachen, 52056, Aachen, Germany.

Alexander Ricke (A)

Department of Organic Chemistry, Arrhenius Laboratory, Stockholm University, 10691, Stockholm, Sweden.

Michael Oschmann (M)

Department of Organic Chemistry, Arrhenius Laboratory, Stockholm University, 10691, Stockholm, Sweden.

Oscar Verho (O)

Department of Organic Chemistry, Arrhenius Laboratory, Stockholm University, 10691, Stockholm, Sweden.

Classifications MeSH