Air-stable redox-active nanomagnets with lanthanide spins radical-bridged by a metal-metal bond.


Journal

Nature communications
ISSN: 2041-1723
Titre abrégé: Nat Commun
Pays: England
ID NLM: 101528555

Informations de publication

Date de publication:
04 02 2019
Historique:
received: 09 10 2018
accepted: 11 01 2019
entrez: 6 2 2019
pubmed: 6 2 2019
medline: 6 2 2019
Statut: epublish

Résumé

Engineering intramolecular exchange interactions between magnetic metal atoms is a ubiquitous strategy for designing molecular magnets. For lanthanides, the localized nature of 4f electrons usually results in weak exchange coupling. Mediating magnetic interactions between lanthanide ions via radical bridges is a fruitful strategy towards stronger coupling. In this work we explore the limiting case when the role of a radical bridge is played by a single unpaired electron. We synthesize an array of air-stable Ln

Identifiants

pubmed: 30718550
doi: 10.1038/s41467-019-08513-6
pii: 10.1038/s41467-019-08513-6
pmc: PMC6362165
doi:

Types de publication

Journal Article Research Support, Non-U.S. Gov't

Langues

eng

Pagination

571

Subventions

Organisme : European Research Council
ID : 648295
Pays : International

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Auteurs

Fupin Liu (F)

Leibniz Institute for Solid State and Materials Research (IFW Dresden), Helmholtzstrasse 20, 01069, Dresden, Germany. f.liu@ifw-dresden.de.

Georgios Velkos (G)

Leibniz Institute for Solid State and Materials Research (IFW Dresden), Helmholtzstrasse 20, 01069, Dresden, Germany.

Denis S Krylov (DS)

Leibniz Institute for Solid State and Materials Research (IFW Dresden), Helmholtzstrasse 20, 01069, Dresden, Germany.

Lukas Spree (L)

Leibniz Institute for Solid State and Materials Research (IFW Dresden), Helmholtzstrasse 20, 01069, Dresden, Germany.

Michal Zalibera (M)

Institute of Physical Chemistry and Chemical Physics, Slovak University of Technology, Radlinského 9, 81237, Bratislava, Slovakia.

Rajyavardhan Ray (R)

Leibniz Institute for Solid State and Materials Research (IFW Dresden), Helmholtzstrasse 20, 01069, Dresden, Germany.
Dresden Center for Computational Materials Science (DCMS), TU Dresden, D-01062, Dresden, Germany.

Nataliya A Samoylova (NA)

Leibniz Institute for Solid State and Materials Research (IFW Dresden), Helmholtzstrasse 20, 01069, Dresden, Germany.

Chia-Hsiang Chen (CH)

Leibniz Institute for Solid State and Materials Research (IFW Dresden), Helmholtzstrasse 20, 01069, Dresden, Germany.

Marco Rosenkranz (M)

Leibniz Institute for Solid State and Materials Research (IFW Dresden), Helmholtzstrasse 20, 01069, Dresden, Germany.

Sandra Schiemenz (S)

Leibniz Institute for Solid State and Materials Research (IFW Dresden), Helmholtzstrasse 20, 01069, Dresden, Germany.

Frank Ziegs (F)

Leibniz Institute for Solid State and Materials Research (IFW Dresden), Helmholtzstrasse 20, 01069, Dresden, Germany.

Konstantin Nenkov (K)

Leibniz Institute for Solid State and Materials Research (IFW Dresden), Helmholtzstrasse 20, 01069, Dresden, Germany.

Aram Kostanyan (A)

Physik-Institut der Universität Zürich, Winterthurerstrasse 190, CH-8057, Zürich, Switzerland.

Thomas Greber (T)

Physik-Institut der Universität Zürich, Winterthurerstrasse 190, CH-8057, Zürich, Switzerland.

Anja U B Wolter (AUB)

Leibniz Institute for Solid State and Materials Research (IFW Dresden), Helmholtzstrasse 20, 01069, Dresden, Germany.

Manuel Richter (M)

Leibniz Institute for Solid State and Materials Research (IFW Dresden), Helmholtzstrasse 20, 01069, Dresden, Germany.
Dresden Center for Computational Materials Science (DCMS), TU Dresden, D-01062, Dresden, Germany.

Bernd Büchner (B)

Leibniz Institute for Solid State and Materials Research (IFW Dresden), Helmholtzstrasse 20, 01069, Dresden, Germany.

Stanislav M Avdoshenko (SM)

Leibniz Institute for Solid State and Materials Research (IFW Dresden), Helmholtzstrasse 20, 01069, Dresden, Germany. s.avdoshenko@ifw-dresden.de.

Alexey A Popov (AA)

Leibniz Institute for Solid State and Materials Research (IFW Dresden), Helmholtzstrasse 20, 01069, Dresden, Germany. a.popov@ifw-dresden.de.

Classifications MeSH