Reticular Access to Highly Porous acs-MOFs with Rigid Trigonal Prismatic Linkers for Water Sorption.
Journal
Journal of the American Chemical Society
ISSN: 1520-5126
Titre abrégé: J Am Chem Soc
Pays: United States
ID NLM: 7503056
Informations de publication
Date de publication:
20 02 2019
20 02 2019
Historique:
pubmed:
9
2
2019
medline:
9
2
2019
entrez:
9
2
2019
Statut:
ppublish
Résumé
Metal-organic frameworks (MOFs) based on edge-transitive 6-c acs nets are well-developed and can be synthesized from trinuclear metal clusters and ditopic ligands, i.e., MOF-235 and MIL-88. The rational design of noncatenated acs-MOFs by symmetry-matching between trigonal prismatic organic ligands and trinuclear clusters, however, remains a great challenge. Herein, we report a series of acs-MOFs (NU-1500) based on trivalent trinuclear metal (Fe
Identifiants
pubmed: 30735359
doi: 10.1021/jacs.8b13710
doi:
Types de publication
Journal Article
Research Support, U.S. Gov't, Non-P.H.S.
Research Support, Non-U.S. Gov't
Langues
eng
Sous-ensembles de citation
IM