How antagonistic salts cause nematic ordering and behave like diblock copolymers.


Journal

The Journal of chemical physics
ISSN: 1089-7690
Titre abrégé: J Chem Phys
Pays: United States
ID NLM: 0375360

Informations de publication

Date de publication:
14 Feb 2019
Historique:
entrez: 17 2 2019
pubmed: 17 2 2019
medline: 17 2 2019
Statut: ppublish

Résumé

We present simulation results and an explanatory theory on how antagonistic salts affect the spinodal decomposition of binary fluid mixtures. We find that spinodal decomposition is arrested and complex structures form only when electrostatic ion-ion interactions are small. In this case, the fluid and ion concentrations couple and the charge field can be approximated as a polynomial function of the relative fluid concentrations alone. When the solvation energy associated with transferring an ion from one fluid phase to the other is of the order of a few k

Identifiants

pubmed: 30769987
doi: 10.1063/1.5085660
doi:

Types de publication

Journal Article

Langues

eng

Pagination

064912

Auteurs

David Jung (D)

Forschungszentrum Jülich, Helmholtz Institute Erlangen-Nürnberg for Renewable Energy (IEK-11), Fürther Straße 248, 90429 Nürnberg, Germany.

Nicolas Rivas (N)

Forschungszentrum Jülich, Helmholtz Institute Erlangen-Nürnberg for Renewable Energy (IEK-11), Fürther Straße 248, 90429 Nürnberg, Germany.

Jens Harting (J)

Forschungszentrum Jülich, Helmholtz Institute Erlangen-Nürnberg for Renewable Energy (IEK-11), Fürther Straße 248, 90429 Nürnberg, Germany.

Classifications MeSH