Charge extraction via graded doping of hole transport layers gives highly luminescent and stable metal halide perovskite devices.


Journal

Science advances
ISSN: 2375-2548
Titre abrégé: Sci Adv
Pays: United States
ID NLM: 101653440

Informations de publication

Date de publication:
Feb 2019
Historique:
received: 23 08 2018
accepted: 27 12 2018
entrez: 23 2 2019
pubmed: 23 2 2019
medline: 23 2 2019
Statut: epublish

Résumé

One source of instability in perovskite solar cells (PSCs) is interfacial defects, particularly those that exist between the perovskite and the hole transport layer (HTL). We demonstrate that thermally evaporated dopant-free tetracene (120 nm) on top of the perovskite layer, capped with a lithium-doped Spiro-OMeTAD layer (200 nm) and top gold electrode, offers an excellent hole-extracting stack with minimal interfacial defect levels. For a perovskite layer interfaced between these graded HTLs and a mesoporous TiO

Identifiants

pubmed: 30793032
doi: 10.1126/sciadv.aav2012
pii: aav2012
pmc: PMC6377269
doi:

Types de publication

Journal Article

Langues

eng

Pagination

eaav2012

Références

Org Lett. 2003 Nov 13;5(23):4245-8
pubmed: 14601971
Adv Mater. 2010 Dec 7;22(46):5301-5
pubmed: 20872410
J Am Chem Soc. 2011 Dec 14;133(49):19944-52
pubmed: 22084927
J Am Chem Soc. 2013 Sep 11;135(36):13538-48
pubmed: 23885856
Science. 2014 Aug 1;345(6196):542-6
pubmed: 25082698
Nat Mater. 2014 Nov;13(11):1039-43
pubmed: 25282507
Nat Mater. 2014 Nov;13(11):1033-8
pubmed: 25282509
Nat Chem. 2015 Sep;7(9):703-11
pubmed: 26291941
Science. 2015 Nov 20;350(6263):944-8
pubmed: 26516198
ACS Nano. 2015 Dec 22;9(12):11863-71
pubmed: 26548399
ACS Nano. 2016 Jan 26;10(1):218-24
pubmed: 26679510
ACS Nano. 2016 Jun 28;10(6):6306-14
pubmed: 27187798
J Phys Chem Lett. 2016 Aug 18;7(16):3264-9
pubmed: 27472458
Science. 2016 Oct 14;354(6309):206-209
pubmed: 27708053
Nano Lett. 2016 Nov 9;16(11):7155-7162
pubmed: 27776210
ACS Appl Mater Interfaces. 2016 Dec 21;8(50):34414-34421
pubmed: 27935300
Nat Mater. 2017 Mar;16(3):356-362
pubmed: 27941806
Nat Commun. 2016 Dec 23;7:13941
pubmed: 28008917
Adv Mater. 2017 Jan;29(2):
pubmed: 28066989
J Vis Exp. 2017 Mar 19;(121):
pubmed: 28362369
Nat Commun. 2017 Jun 01;8:15684
pubmed: 28569749
Science. 2017 Nov 10;358(6364):768-771
pubmed: 28971968
J Phys Chem Lett. 2018 Apr 5;9(7):1703-1711
pubmed: 29537271
Nature. 2018 Mar 21;555(7697):497-501
pubmed: 29565365
Nat Mater. 2018 May;17(5):372-376
pubmed: 29686248
ACS Nano. 2018 Jul 24;12(7):7301-7311
pubmed: 29953817

Auteurs

Mojtaba Abdi-Jalebi (M)

Cavendish Laboratory, Department of Physics, University of Cambridge, JJ Thomson Avenue, Cambridge CB3 0HE, UK.

M Ibrahim Dar (M)

Cavendish Laboratory, Department of Physics, University of Cambridge, JJ Thomson Avenue, Cambridge CB3 0HE, UK.
Laboratory of Photonics and Interfaces, Institute of Chemical Sciences and Engineering, École Polytechnique Fédérale de Lausanne, Lausanne CH-1015, Switzerland.

Satyaprasad P Senanayak (SP)

Cavendish Laboratory, Department of Physics, University of Cambridge, JJ Thomson Avenue, Cambridge CB3 0HE, UK.

Aditya Sadhanala (A)

Cavendish Laboratory, Department of Physics, University of Cambridge, JJ Thomson Avenue, Cambridge CB3 0HE, UK.
Clarendon Laboratory, Department of Physics, University of Oxford, Parks Road, Oxford OX1 3PU, UK.

Zahra Andaji-Garmaroudi (Z)

Cavendish Laboratory, Department of Physics, University of Cambridge, JJ Thomson Avenue, Cambridge CB3 0HE, UK.

Luis M Pazos-Outón (LM)

Cavendish Laboratory, Department of Physics, University of Cambridge, JJ Thomson Avenue, Cambridge CB3 0HE, UK.
Department of Electrical Engineering and Computer Sciences, University of California, Berkeley, CA 94720, USA.

Johannes M Richter (JM)

Cavendish Laboratory, Department of Physics, University of Cambridge, JJ Thomson Avenue, Cambridge CB3 0HE, UK.

Andrew J Pearson (AJ)

Cavendish Laboratory, Department of Physics, University of Cambridge, JJ Thomson Avenue, Cambridge CB3 0HE, UK.

Henning Sirringhaus (H)

Cavendish Laboratory, Department of Physics, University of Cambridge, JJ Thomson Avenue, Cambridge CB3 0HE, UK.

Michael Grätzel (M)

Laboratory of Photonics and Interfaces, Institute of Chemical Sciences and Engineering, École Polytechnique Fédérale de Lausanne, Lausanne CH-1015, Switzerland.

Richard H Friend (RH)

Cavendish Laboratory, Department of Physics, University of Cambridge, JJ Thomson Avenue, Cambridge CB3 0HE, UK.

Classifications MeSH