Catalyst-Free Deaminative Functionalizations of Primary Amines by Photoinduced Single-Electron Transfer.
Giese reactions
deamination
electron donor-acceptor complexes
photochemistry
radical reactions
Journal
Angewandte Chemie (International ed. in English)
ISSN: 1521-3773
Titre abrégé: Angew Chem Int Ed Engl
Pays: Germany
ID NLM: 0370543
Informations de publication
Date de publication:
16 04 2019
16 04 2019
Historique:
received:
02
01
2019
pubmed:
23
2
2019
medline:
23
2
2019
entrez:
23
2
2019
Statut:
ppublish
Résumé
The use of pyridinium-activated primary amines as photoactive functional groups for deaminative generation of alkyl radicals under catalyst-free conditions is described. By taking advantage of the visible light absorptivity of electron donor-acceptor complexes between Katritzky pyridinium salts and either Hantzsch ester or Et
Identifiants
pubmed: 30794331
doi: 10.1002/anie.201814452
pmc: PMC6492299
doi:
Types de publication
Journal Article
Research Support, Non-U.S. Gov't
Langues
eng
Sous-ensembles de citation
IM
Pagination
5697-5701Subventions
Organisme : Overseas Scholarship Program of Shaanxi Normal University
Pays : International
Organisme : H2020 European Research Council
ID : 670668
Pays : International
Organisme : The Fundamental Research Funds for the Central Universities (CN)
ID : GK201603034
Pays : International
Organisme : Engineering and Physical Sciences Research Council
ID : EP/I038071/1
Pays : International
Organisme : University of Auckland Doctoral Scholarship
Pays : International
Organisme : Engineering and Physical Sciences Research Council
ID : EP/R004978/1
Pays : International
Organisme : Biotechnology and Biological Sciences Research Council
ID : BB/F011539/1
Pays : United Kingdom
Informations de copyright
© 2019 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA.
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