Phosphazene Base tBu-P4 Catalyzed Methoxy-Alkoxy Exchange Reaction on (Hetero)Arenes.
alcohols
aromatic substitution
methoxyarenes
organocatalysis
phosphazenes
Journal
Chemistry (Weinheim an der Bergstrasse, Germany)
ISSN: 1521-3765
Titre abrégé: Chemistry
Pays: Germany
ID NLM: 9513783
Informations de publication
Date de publication:
26 Apr 2019
26 Apr 2019
Historique:
received:
01
02
2019
revised:
22
02
2019
pubmed:
27
2
2019
medline:
27
2
2019
entrez:
27
2
2019
Statut:
ppublish
Résumé
The organic superbase tBu-P4 catalyzes methoxy-alkoxy exchange reactions on (hetero)arenes with alcohols. The catalytic reaction proceeded efficiently with electron-deficient methoxy(hetero)arenes as well as with a variety of alcohols, including 3-amino-1-propanol, β-citronellol, menthol, and cholesterol. An intramolecular version of this reaction furnished six- and seven-membered ring compounds.
Identifiants
pubmed: 30807672
doi: 10.1002/chem.201900498
doi:
Types de publication
Journal Article
Langues
eng
Pagination
6077-6081Informations de copyright
© 2019 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.