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Y zeolite enthalpy of adsorption entropy of adsorption in situ studies principal component analysis

Journal

Acta crystallographica. Section A, Foundations and advances
ISSN: 2053-2733
Titre abrégé: Acta Crystallogr A Found Adv
Pays: United States
ID NLM: 101620182

Informations de publication

Date de publication:
01 Mar 2019
Historique:
received: 23 07 2018
accepted: 12 12 2018
entrez: 2 3 2019
pubmed: 2 3 2019
medline: 2 3 2019
Statut: ppublish

Résumé

The increasing efficiency of detectors and brightness of X-rays in both laboratory and large-scale facilities allow the collection of full single-crystal X-ray data sets within minutes. The analysis of these `crystallographic big data' requires new tools and approaches. To answer these needs, the use of principal component analysis (PCA) is proposed to improve the efficiency and speed of the analysis. Potentialities and limitations of PCA were investigated using single-crystal X-ray diffraction (XRD) data collected in situ on Y zeolite, in which CO

Identifiants

pubmed: 30821256
pii: S2053273318017618
doi: 10.1107/S2053273318017618
pmc: PMC6396398
doi:

Types de publication

Journal Article

Langues

eng

Pagination

214-222

Informations de copyright

open access.

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Auteurs

Eleonora Conterosito (E)

Dipartimento di Scienze e Innovazione Tecnologica, Università del Piemonte Orientale, Via Michel 11, Alessandria 15121, Italy.

Luca Palin (L)

Dipartimento di Scienze e Innovazione Tecnologica, Università del Piemonte Orientale, Via Michel 11, Alessandria 15121, Italy.

Rocco Caliandro (R)

Institute of Crystallography, CNR, via Amendola 122/o, Bari 70126, Italy.

Wouter van Beek (W)

Swiss-Norwegian Beamlines, ESRF, The European Synchrotron, CS40220, Grenoble 38043, France.

Dmitry Chernyshov (D)

Swiss-Norwegian Beamlines, ESRF, The European Synchrotron, CS40220, Grenoble 38043, France.

Marco Milanesio (M)

Dipartimento di Scienze e Innovazione Tecnologica, Università del Piemonte Orientale, Via Michel 11, Alessandria 15121, Italy.

Classifications MeSH