Uranyl-Peroxide Capsule Self-Assembly in Slow Motion.

X-ray scattering calorimetry crystal structure polyoxometalates uranyl

Journal

Chemistry (Weinheim an der Bergstrasse, Germany)
ISSN: 1521-3765
Titre abrégé: Chemistry
Pays: Germany
ID NLM: 9513783

Informations de publication

Date de publication:
26 Apr 2019
Historique:
received: 14 12 2018
revised: 05 03 2019
pubmed: 7 3 2019
medline: 7 3 2019
entrez: 7 3 2019
Statut: ppublish

Résumé

Uranyl-peroxide capsules are the newest family of polyoxometalates. Although discovered 13 years previously with over 70 topologies reported, there is a lack in the fundamental understanding of assembly mechanisms, particularly the role of the alkali counterions. Herein, the reaction pathway and assembly of uranyl peroxide capsules is reported by tracking the conversion from K

Identifiants

pubmed: 30840324
doi: 10.1002/chem.201806227
doi:

Types de publication

Journal Article

Langues

eng

Pagination

6087-6091

Subventions

Organisme : National Nuclear Security Administration
ID : DE-NA0003763
Organisme : Basic Energy Sciences
ID : DE-SC0001089

Informations de copyright

© 2019 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

Auteurs

Ana Arteaga (A)

Department of Chemistry, Oregon State University, Corvallis, OR, 97330, USA.

Lei Zhang (L)

Department of Civil and Environmental Engineering and Earth Sciences, University of Notre Dame, Notre Dame, IN, 46556, USA.

Sarah Hickam (S)

Department of Civil and Environmental Engineering and Earth Sciences, University of Notre Dame, Notre Dame, IN, 46556, USA.

Mateusz Dembowski (M)

Department of Civil and Environmental Engineering and Earth Sciences, University of Notre Dame, Notre Dame, IN, 46556, USA.
Current address: Pacific Northwest National Laboratory, Richland, WA, 99352, USA.

Peter C Burns (PC)

Department of Civil and Environmental Engineering and Earth Sciences, University of Notre Dame, Notre Dame, IN, 46556, USA.

May Nyman (M)

Department of Chemistry, Oregon State University, Corvallis, OR, 97330, USA.

Classifications MeSH