Atomic electrostatic maps of 1D channels in 2D semiconductors using 4D scanning transmission electron microscopy.


Journal

Nature communications
ISSN: 2041-1723
Titre abrégé: Nat Commun
Pays: England
ID NLM: 101528555

Informations de publication

Date de publication:
08 03 2019
Historique:
received: 18 12 2018
accepted: 01 02 2019
entrez: 10 3 2019
pubmed: 10 3 2019
medline: 10 3 2019
Statut: epublish

Résumé

Defects in materials give rise to fluctuations in electrostatic fields that reflect the local charge density, but imaging this with single atom sensitivity is challenging. However, if possible, this provides information about the energetics of adatom binding, localized conduction channels, molecular functionality and their relationship to individual bonds. Here, ultrastable electron-optics are combined with a high-speed 2D electron detector to map electrostatic fields around individual atoms in 2D monolayers using 4D scanning transmission electron microscopy. Simultaneous imaging of the electric field, phase, annular dark field and the total charge in 2D MoS

Identifiants

pubmed: 30850616
doi: 10.1038/s41467-019-08904-9
pii: 10.1038/s41467-019-08904-9
pmc: PMC6408534
doi:

Types de publication

Journal Article Research Support, U.S. Gov't, Non-P.H.S.

Langues

eng

Pagination

1127

Références

Ultramicroscopy. 2009 Sep;109(10):1256-62
pubmed: 19541420
Nat Commun. 2014 Dec 15;5:5653
pubmed: 25501385
Nat Mater. 2011 Mar;10(3):209-15
pubmed: 21240288
Small. 2018 Mar;14(13):e1703727
pubmed: 29411935
Ultramicroscopy. 2017 Nov;182:169-178
pubmed: 28692934
Microscopy (Oxf). 2013 Feb;62(1):23-41
pubmed: 23390310
ACS Nano. 2018 Aug 28;12(8):7721-7730
pubmed: 30117727
ACS Nano. 2016 May 24;10(5):5419-30
pubmed: 27159415
ACS Nano. 2018 Sep 25;12(9):8875-8881
pubmed: 30074756
Phys Rev B Condens Matter. 1996 Oct 15;54(16):11169-11186
pubmed: 9984901
Nat Commun. 2017 May 30;8:15631
pubmed: 28555629
Phys Rev B Condens Matter. 1994 Dec 15;50(24):17953-17979
pubmed: 9976227
Phys Rev Lett. 1996 Oct 28;77(18):3865-3868
pubmed: 10062328
Ultramicroscopy. 2016 Oct;169:107-121
pubmed: 27517162
Nano Lett. 2018 Jun 13;18(6):3746-3751
pubmed: 29775315
Nat Commun. 2018 Sep 24;9(1):3878
pubmed: 30250209
Ultramicroscopy. 2016 Jan;160:265-280
pubmed: 26590505
Nat Commun. 2016 Aug 26;7:12532
pubmed: 27561914
Acc Chem Res. 2017 Jul 18;50(7):1502-1512
pubmed: 28677953
ACS Nano. 2015 Aug 25;9(8):8599-608
pubmed: 26204434
Ultramicroscopy. 2017 Nov;182:44-53
pubmed: 28654827
Nat Commun. 2012 Mar 06;3:730
pubmed: 22395621
Phys Rev B Condens Matter. 1992 Jun 15;45(23):13244-13249
pubmed: 10001404
Nature. 2018 Jul;559(7714):343-349
pubmed: 30022131
Ultramicroscopy. 2015 Dec;159 Pt 1:124-37
pubmed: 26381331
Adv Struct Chem Imaging. 2018;4(1):10
pubmed: 30221126

Auteurs

Shiang Fang (S)

Department of Physics, Harvard University, Cambridge, MA, 02138, USA.

Yi Wen (Y)

Department of Materials, University of Oxford, 16 Parks Road, Oxford, OX1 3PH, UK.

Christopher S Allen (CS)

Department of Materials, University of Oxford, 16 Parks Road, Oxford, OX1 3PH, UK.
Electron Physical Sciences Imaging Center, Diamond Light Source Ltd., Didcot, Oxfordshire, OX11 0DE, UK.

Colin Ophus (C)

National Center for Electron Microscopy, Molecular Foundry, Lawrence Berkeley National Laboratory, 1 Cyclotron Road, Berkeley, 94720, CA, USA.

Grace G D Han (GGD)

Department of Chemistry, Brandeis University, Waltham, 02453, MA, USA.

Angus I Kirkland (AI)

Department of Materials, University of Oxford, 16 Parks Road, Oxford, OX1 3PH, UK.
Electron Physical Sciences Imaging Center, Diamond Light Source Ltd., Didcot, Oxfordshire, OX11 0DE, UK.

Efthimios Kaxiras (E)

Department of Physics, Harvard University, Cambridge, MA, 02138, USA. kaxiras@physics.harvard.edu.
John A. Paulson School of Engineering and Applied Sciences, Harvard University, Cambridge, MA, 02138, USA. kaxiras@physics.harvard.edu.

Jamie H Warner (JH)

Department of Materials, University of Oxford, 16 Parks Road, Oxford, OX1 3PH, UK. Jamie.warner@materials.ox.ac.uk.

Classifications MeSH