Homonuclear ADAPT: A general preparation route to long-lived nuclear singlet order.

ADAPT Long-lived state M2S SLIC Sarkar sequence Singlet order

Journal

Journal of magnetic resonance (San Diego, Calif. : 1997)
ISSN: 1096-0856
Titre abrégé: J Magn Reson
Pays: United States
ID NLM: 9707935

Informations de publication

Date de publication:
Apr 2019
Historique:
received: 26 10 2018
revised: 27 01 2019
accepted: 26 02 2019
pubmed: 10 3 2019
medline: 10 3 2019
entrez: 10 3 2019
Statut: ppublish

Résumé

We introduce a simple strategy to access and readout nuclear singlet order based on the alternate repetition of hard pulses and delays. We demonstrate the general applicability of the method by accessing nuclear singlet order in spin systems characterized by diverse coupling regimes. We show that the method is highly efficient in the strong-coupling and chemical equivalence regimes, and can overcome some limitations of other well-established and more elaborated pulse sequences. A simulation package is provided which allows the determination of pulse sequence parameters.

Identifiants

pubmed: 30851665
pii: S1090-7807(19)30029-1
doi: 10.1016/j.jmr.2019.02.005
pii:
doi:

Types de publication

Journal Article

Langues

eng

Pagination

49-55

Informations de copyright

Copyright © 2019 Elsevier Inc. All rights reserved.

Auteurs

Stuart J Elliott (SJ)

School of Chemistry, University of Southampton, Southampton SO17 1BJ, United Kingdom.

Gabriele Stevanato (G)

Institut des Sciences et Ingénierie Chimiques, Ecole Polytechnique Fédérale de Lausanne (EPFL), Batochime, CH-1015 Lausanne, Switzerland. Electronic address: gabriele.stevanato@epfl.ch.

Classifications MeSH