A Trigonal Prismatic Cobalt(II) Complex as a Single Molecule Magnet with a Reduced Contribution from Quantum Tunneling.
THz-EPR spectroscopy
cage compounds
high-spin cobalt(II) complexes
paramagnetic NMR spectroscopy
single molecule magnets
Journal
Chemphyschem : a European journal of chemical physics and physical chemistry
ISSN: 1439-7641
Titre abrégé: Chemphyschem
Pays: Germany
ID NLM: 100954211
Informations de publication
Date de publication:
16 04 2019
16 04 2019
Historique:
received:
05
03
2019
pubmed:
22
3
2019
medline:
22
3
2019
entrez:
22
3
2019
Statut:
ppublish
Résumé
Herein, we report a new trigonal prismatic cobalt(II) complex that behaves as a single molecule magnet. The obtained zero-field splitting, which is also directly accessed by THz-EPR spectroscopy (-102.5 cm
Identifiants
pubmed: 30897255
doi: 10.1002/cphc.201900219
doi:
Types de publication
Journal Article
Research Support, U.S. Gov't, Non-P.H.S.
Research Support, Non-U.S. Gov't
Langues
eng
Pagination
1001-1005Subventions
Organisme : Russian Science Foundation
ID : 17-73-20369
Pays : International
Organisme : National Science Foundation Cooperative Agreement
ID : DMR-1644779
Pays : International
Informations de copyright
© 2019 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.