Contemporary Chemistry of Berkelium and Californium.
actinides
berkelium complexation
californium complexation
coordination chemistry
Journal
Chemistry (Weinheim an der Bergstrasse, Germany)
ISSN: 1521-3765
Titre abrégé: Chemistry
Pays: Germany
ID NLM: 9513783
Informations de publication
Date de publication:
06 Aug 2019
06 Aug 2019
Historique:
received:
07
02
2019
pubmed:
26
3
2019
medline:
26
3
2019
entrez:
26
3
2019
Statut:
ppublish
Résumé
The merging of small-scale syntheses and rapid crystallization methods have provided access to crystalline samples of berkelium (Z=97) and californium (Z=98) coordination complexes and compounds that can be interrogated with a suite of spectroscopic tools and structural elucidation approaches that have come online over the last 20 years. The combination of this experimental data with relativistic theoretical methods that capture the effects of spin-orbit coupling and scalar relativistic effects have allowed us to understand the electronic structure of berkelium and californium compounds at a level of detail that was not previously possible. The harbinger of this new era of post-curium chemistry was the synthesis and characterization of [Cf{B
Identifiants
pubmed: 30908747
doi: 10.1002/chem.201900586
doi:
Types de publication
Journal Article
Review
Langues
eng
Sous-ensembles de citation
IM
Pagination
10251-10261Subventions
Organisme : U.S. Department of Energy
ID : DE-FG02-13ER16414
Informations de copyright
© 2019 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.