Unsaturated vicinal frustrated phosphane/borane Lewis pairs as ligands in gold(i) chemistry.

The P/B FLP 6, formed by the 1,1-hydroboration of dimesitylphosphino(trimethylsilyl)acetylene with HB(C6F5)2 forms the Au(i)X complexes 9a (X: Cl) and 10a (X: NTf2), respectively. Both show marked AuB interactions. The P/B FLP isomer 8, featuring the bulky SiMe3 substituent at the carbon adjacent to boron forms gold complexes 9b and 10b, both of which show weaker AuB interactions. Complex 10a was employed in the catalytic hydroamination of a series of alkynes with p-toluidine. Complexes 9 and 10 were characterized by X-ray diffraction.