Cyanine Modification Tuned for Amine Photorelease.


Journal

Photochemistry and photobiology
ISSN: 1751-1097
Titre abrégé: Photochem Photobiol
Pays: United States
ID NLM: 0376425

Informations de publication

Date de publication:
09 2019
Historique:
received: 04 03 2019
accepted: 19 03 2019
pubmed: 31 3 2019
medline: 13 3 2020
entrez: 31 3 2019
Statut: ppublish

Résumé

Cyanines are emerging as useful agents for photoreleasing biological compounds because of their capability of utilizing near-infrared (NIR) light. Another benefit is their ability to self-sensitize to produce singlet oxygen for the release of aryl amines, a process that has not been as feasible in the past. Here, we highlight the paper by Schnermann et al. (https://doi.org/10.1111/php.13090), which reports on a cyanine conjugate for heterolytic photocleavage of aryl amines. This paper is timely-delving into a photorelease mechanism involving a domino rearrangement and β-elimination triggered by NIR light.

Identifiants

pubmed: 30927440
doi: 10.1111/php.13102
doi:

Types de publication

Journal Article Research Support, U.S. Gov't, Non-P.H.S. Comment

Langues

eng

Sous-ensembles de citation

IM

Pagination

1280-1282

Commentaires et corrections

Type : CommentOn

Informations de copyright

© 2019 American Society for Photobiology.

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Auteurs

Joel P Mathew (JP)

Department of Chemistry, Brooklyn College of the City University of New York, Brooklyn, NY.

Alexander Greer (A)

Department of Chemistry, Brooklyn College of the City University of New York, Brooklyn, NY.
Ph.D. Program in Chemistry, The Graduate Center of the City University of New York, New York, NY.

Classifications MeSH