General, Practical and Selective Oxidation Protocol for CF₃S into CF₃S(O) Group.
dihydrogen peroxide
oxidation
trifluoromethylsulfides
trifluoromethylsulfoxides
trifluoroperacetic acid
Journal
Molecules (Basel, Switzerland)
ISSN: 1420-3049
Titre abrégé: Molecules
Pays: Switzerland
ID NLM: 100964009
Informations de publication
Date de publication:
30 Mar 2019
30 Mar 2019
Historique:
received:
14
03
2019
revised:
25
03
2019
accepted:
27
03
2019
entrez:
3
4
2019
pubmed:
3
4
2019
medline:
3
1
2020
Statut:
epublish
Résumé
A simple and efficient protocol for the oxidation of trifluoromethyl, mono- and difluoromethyl sulfides to the corresponding sulfoxides without over-oxidation to sulfones, using TFPAA prepared in situ from trifluoroacetic acid and 15% H₂O₂ aqueous solution was developed. The methodology is suitable for a wide range of aromatic and aliphatic substrates in milligram and multigram scales.
Identifiants
pubmed: 30935001
pii: molecules24071249
doi: 10.3390/molecules24071249
pmc: PMC6479840
pii:
doi:
Substances chimiques
Fluorine Compounds
0
Oxides
0
Sulfides
0
Sulfones
0
Sulfoxides
0
Water
059QF0KO0R
Hydrogen Peroxide
BBX060AN9V
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Références
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