Oxidative Coupling of 3-Oxindoles with Indoles and Arenes.
catalysis
coinage metals
oxidative coupling
oxygen
sustainable
Journal
ChemSusChem
ISSN: 1864-564X
Titre abrégé: ChemSusChem
Pays: Germany
ID NLM: 101319536
Informations de publication
Date de publication:
05 Jul 2019
05 Jul 2019
Historique:
received:
14
02
2019
revised:
03
04
2019
pubmed:
5
4
2019
medline:
5
4
2019
entrez:
5
4
2019
Statut:
ppublish
Résumé
A highly efficient method for the oxidative coupling of 2-substituted 3-oxindoles with aromatic compounds to form 2,2-disubstituted indolin-3-ones with broad scope is described. This work utilized oxygen as the terminal oxidant and a base-metal catalyst under mild conditions instead of toxic/precious-metal reagents and higher-molecular-weight oxidants. Quaternary structures were produced in modest-to-excellent yields (up to 96 %) without prefunctionalization.
Identifiants
pubmed: 30945447
doi: 10.1002/cssc.201900438
pmc: PMC6703824
mid: NIHMS1032889
doi:
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Pagination
3144-3151Subventions
Organisme : Directorate for Biological Sciences
ID : CHE1764298)
Organisme : NCRR NIH HHS
ID : S10 RR023444
Pays : United States
Organisme : NIH HHS
ID : GM-112684
Pays : United States
Organisme : NCRR NIH HHS
ID : S10 RR022442
Pays : United States
Organisme : NIGMS NIH HHS
ID : R01 GM112684
Pays : United States
Organisme : NIH HHS
ID : S10 OD011980
Pays : United States
Informations de copyright
© 2019 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.
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