Rational design of an argon-binding superelectrophilic anion.
Ar compounds
dodecaborates
multiple-charged anions
photoelectron spectroscopy
superelectrophilic anions
Journal
Proceedings of the National Academy of Sciences of the United States of America
ISSN: 1091-6490
Titre abrégé: Proc Natl Acad Sci U S A
Pays: United States
ID NLM: 7505876
Informations de publication
Date de publication:
23 04 2019
23 04 2019
Historique:
pubmed:
7
4
2019
medline:
7
4
2019
entrez:
7
4
2019
Statut:
ppublish
Résumé
Chemically binding to argon (Ar) at room temperature has remained the privilege of the most reactive electrophiles, all of which are cationic (or even dicationic) in nature. Herein, we report a concept for the rational design of anionic superelectrophiles that are composed of a strong electrophilic center firmly embedded in a negatively charged framework of exceptional stability. To validate our concept, we synthesized the percyano-dodecoborate [B
Identifiants
pubmed: 30952786
pii: 1820812116
doi: 10.1073/pnas.1820812116
pmc: PMC6486711
doi:
Types de publication
Journal Article
Research Support, Non-U.S. Gov't
Langues
eng
Sous-ensembles de citation
IM
Pagination
8167-8172Déclaration de conflit d'intérêts
The authors declare no conflict of interest.
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