van der Waals exchange-correlation functionals over bulk and surface properties of transition metals.

The correct description of van der Waals (vdW) interaction forces is required for accurately describing dispersion bonded systems. Several approaches have been proposed to include London dispersion in density functional theory exchange-correlation functionals, where the family of so-called van der Waals (vdW-DF) exchange-correlation functionals have shown a better performance than local or semi local exchange-correlation functionals for describing molecular adsorption on metals. Despite the numerous benchmarks performed with these functionals, their performance in predicting bulk properties of transition metals has hitherto not been investigated in detail. We have therefore tested five vdW-DF exchange-correlation functionals, vdW-DF2, optPBE-vdW, BEEF-vdW, optB88-vdW and C09