Hollow nanoreactors for Pd-catalyzed Suzuki-Miyaura coupling and
Journal
Chemical science
ISSN: 2041-6520
Titre abrégé: Chem Sci
Pays: England
ID NLM: 101545951
Informations de publication
Date de publication:
07 Mar 2019
07 Mar 2019
Historique:
received:
03
10
2018
accepted:
25
12
2018
entrez:
19
4
2019
pubmed:
19
4
2019
medline:
19
4
2019
Statut:
epublish
Résumé
We describe the fabrication of hollow microspheres consisting of mesoporous silica nanoshells decorated with an inner layer of palladium nanoparticles and their use as Pd-nanoreactors in aqueous media. These palladium-equipped capsules can be used to promote the uncaging of propargyl-protected phenols, as well as Suzuki-Miyaura cross-coupling, in water and at physiologically compatible temperatures. Importantly, the depropargylation reaction can be accomplished in a bioorthogonal manner in the presence of relatively high concentrations of biomolecular components and even in the presence of mammalian cells.
Identifiants
pubmed: 30996975
doi: 10.1039/c8sc04390f
pii: c8sc04390f
pmc: PMC6419927
doi:
Types de publication
Journal Article
Langues
eng
Pagination
2598-2603Références
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