Origins of Catalyst Inhibition in the Manganese-Catalysed Oxidation of Lignin Model Compounds with H

catalysis inhibition lignin manganese oxidation

Journal

ChemSusChem
ISSN: 1864-564X
Titre abrégé: ChemSusChem
Pays: Germany
ID NLM: 101319536

Informations de publication

Date de publication:
05 Jul 2019
Historique:
received: 10 03 2019
revised: 13 04 2019
pubmed: 20 4 2019
medline: 20 4 2019
entrez: 20 4 2019
Statut: ppublish

Résumé

The upgrading of complex bio-renewable feedstock, such as lignocellulose, through depolymerisation benefits from the selective reactions at key functional groups. Applying homogeneous catalysts developed for selective organic oxidative transformations to complex feedstock such as lignin is challenged by the presence of interfering components. The selection of appropriate model compounds is essential in applying new catalytic systems and identifying such interferences. Here, it was shown by using as an example the oxidation of a model substrate containing a β-O-4 linkage with H

Identifiants

pubmed: 31001914
doi: 10.1002/cssc.201900689
pmc: PMC6617720
doi:

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

3126-3133

Informations de copyright

© 2017 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA.

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Auteurs

Alessia Barbieri (A)

Dipartimento di Chimica, Universita'di Roma "La Sapienza", P.le A. Moro 5, I-00185, Rome, Italy.

Johann B Kasper (JB)

Molecular Inorganic Chemistry, Stratingh Institute for Chemistry, Faculty of Science and Engineering, University of Groningen, Nijenborgh 4, 9747AG, Groningen, The Netherlands.

Francesco Mecozzi (F)

Molecular Inorganic Chemistry, Stratingh Institute for Chemistry, Faculty of Science and Engineering, University of Groningen, Nijenborgh 4, 9747AG, Groningen, The Netherlands.

Osvaldo Lanzalunga (O)

Dipartimento di Chimica, Universita'di Roma "La Sapienza", P.le A. Moro 5, I-00185, Rome, Italy.

Wesley R Browne (WR)

Molecular Inorganic Chemistry, Stratingh Institute for Chemistry, Faculty of Science and Engineering, University of Groningen, Nijenborgh 4, 9747AG, Groningen, The Netherlands.

Classifications MeSH