Tetramethylrhodamine is an essential scaffold of azide probe in detecting cellular acrolein.


Journal

Bioorganic & medicinal chemistry
ISSN: 1464-3391
Titre abrégé: Bioorg Med Chem
Pays: England
ID NLM: 9413298

Informations de publication

Date de publication:
01 06 2019
Historique:
received: 22 03 2019
revised: 15 04 2019
accepted: 17 04 2019
pubmed: 27 4 2019
medline: 23 9 2020
entrez: 27 4 2019
Statut: ppublish

Résumé

Tetramethylrhodamine (TAMRA)-phenyl azide is a chemical probe used to detect intracellular acrolein directly in live cells. Herein, we demonstrated that TAMRA is the optimum fluorophore for the probe. TAMRA-phenyl azide was used to reveal that high levels of acrolein are generated in a variety of breast cancer cells, regardless of the tumor subtype. These findings corroborate the analysis presented in our previous report, in which TAMRA-phenyl azide was used to label breast cancer tissues resected from breast cancer patients. Because high levels of acrolein were generated in all cancer cell types, we believe that acrolein detection may be useful as a general method for labeling cancerous tissues.

Identifiants

pubmed: 31023557
pii: S0968-0896(19)30478-X
doi: 10.1016/j.bmc.2019.04.026
pii:
doi:

Substances chimiques

Azides 0
Biomarkers 0
Fluorescent Dyes 0
Rhodamines 0
tetramethylrhodamine 62669-72-1
Acrolein 7864XYD3JJ

Types de publication

Journal Article Research Support, Non-U.S. Gov't

Langues

eng

Sous-ensembles de citation

IM

Pagination

2228-2234

Informations de copyright

Copyright © 2019 Elsevier Ltd. All rights reserved.

Auteurs

Ambara R Pradipta (AR)

Biofunctional Synthetic Chemistry Laboratory, RIKEN Cluster for Pioneering Research, 2-1 Hirosawa, Wako, Saitama 351-0198, Japan.

Motoko Fujii (M)

Biofunctional Synthetic Chemistry Laboratory, RIKEN Cluster for Pioneering Research, 2-1 Hirosawa, Wako, Saitama 351-0198, Japan.

Tomonori Tanei (T)

Department of Breast and Endocrine Surgery, Graduate School of Medicine, Osaka University, 2-2-E10 Yamadaoka, Suita, Osaka 565-0871, Japan.

Koji Morimoto (K)

Biofunctional Synthetic Chemistry Laboratory, RIKEN Cluster for Pioneering Research, 2-1 Hirosawa, Wako, Saitama 351-0198, Japan.

Kenzo Shimazu (K)

Department of Breast and Endocrine Surgery, Graduate School of Medicine, Osaka University, 2-2-E10 Yamadaoka, Suita, Osaka 565-0871, Japan.

Shinzaburo Noguchi (S)

Department of Breast and Endocrine Surgery, Graduate School of Medicine, Osaka University, 2-2-E10 Yamadaoka, Suita, Osaka 565-0871, Japan.

Katsunori Tanaka (K)

Biofunctional Synthetic Chemistry Laboratory, RIKEN Cluster for Pioneering Research, 2-1 Hirosawa, Wako, Saitama 351-0198, Japan; Biofunctional Chemistry Laboratory, A. Butlerov Institute of Chemistry, Kazan Federal University, 18 Kremlyovskaya Street, Kazan 420008, Russian Federation; GlycoTargeting Research Laboratory, RIKEN Baton Zone Program, 2-1 Hirosawa, Wako, Saitama 351-0198, Japan. Electronic address: kotzenori@riken.jp.

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Classifications MeSH