Pronounced Impact of

CSS SEM XRD band gap ion-exchange p-type carriers semiconductor thin films solar cell

Journal

Materials (Basel, Switzerland)
ISSN: 1996-1944
Titre abrégé: Materials (Basel)
Pays: Switzerland
ID NLM: 101555929

Informations de publication

Date de publication:
25 Apr 2019
Historique:
received: 11 02 2019
revised: 16 04 2019
accepted: 18 04 2019
entrez: 28 4 2019
pubmed: 28 4 2019
medline: 28 4 2019
Statut: epublish

Résumé

Stabilized un-doped Zinc Telluride (ZnTe) thin films were grown on glass substrates under vacuum using a closed space sublimation (CSS) technique. A dilute copper nitrate solution (0.1/100 mL) was prepared for copper doping, known as an ion exchange process, in the matrix of the ZnTe thin film. The reproducible polycrystalline cubic structure of undoped and the Cu doped ZnTe thin films with preferred orientation (111) was confirmed by X-rays diffraction (XRD) technique. Lattice parameter analyses verified the expansion of unit cell volume after incorporation of Cu species into ZnTe thin films samples. The micrographs of scanning electron microscopy (SEM) were used to measure the variation in crystal sizes of samples. The energy dispersive X-rays were used to validate the elemental composition of undoped and Cu-doped ZnTe thin films. The bandgap energy 2.24 eV of the ZnTe thin film decreased after doping Cu to 2.20 eV and may be due to the introduction of acceptors states near to valance band. Optical studies showed that refractive index was measured from 2.18 to 3.24, whereas thicknesses varied between 220 nm to 320 nm for un-doped and Cu doped ZnTe thin film, respectively, using the Swanepoel model. The oxidation states of Zn

Identifiants

pubmed: 31027289
pii: ma12081359
doi: 10.3390/ma12081359
pmc: PMC6515456
pii:
doi:

Types de publication

Journal Article

Langues

eng

Références

J Phys Condens Matter. 2013 Apr 17;25(15):156005
pubmed: 23529084
J Am Chem Soc. 2013 Jul 24;135(29):10618-21
pubmed: 23829658
Sci Rep. 2016 Feb 16;6:21178
pubmed: 26880365
Nat Commun. 2017 Dec 1;8(1):1894
pubmed: 29196617

Auteurs

Waqar Mahmood (W)

Material Synthesis & Characterizations (MSC) Laboratory, Department of Physics, Fatima Jinnah Women University (FJWU), The Mall Rawalpindi 46000, Pakistan. waqarmahmood@fjwu.edu.pk.
Photon Science Institute (PSI), School of Physics and Astronomy, University of Manchester, Oxford Road, Manchester M13 9PL, UK. waqarmahmood@fjwu.edu.pk.
Thin Films Technology (TFT) Research Laboratory, Department of Physics, COMSATS University Islamabad (CUI), Islamabad 44000, Pakistan. waqarmahmood@fjwu.edu.pk.

Saif Ullah Awan (SU)

Department of Electrical Engineering, NUST College of Electrical and Mechanical Engineering, National University of Science and Technology (NUST), Islamabad 44000, Pakistan. ullahphy@gmail.com.

Amad Ud Din (A)

Analog Electronics System (AES) Laboratory, Department of Physics, Fatima Jinnah Women University (FJWU), The Mall Rawalpindi 46000, Pakistan. ammad@fjwu.edu.pk.

Junaid Ali (J)

Department of Physics, COMSATS University Islamabad (CUI), Islamabad 44000, Pakistan. junaid_ali@comsats.edu.pk.

Muhammad Farooq Nasir (MF)

Department of Physics, RIPHAH International University, Islamabad 44000, Pakistan. farooq.nasir@riphah.edu.pk.

Nazakat Ali (N)

Department of Materials Science & Engineering, Institute of Space Technology (IST), Islamabad Highway, Islamabad 44000, Pakistan. nazakat@ist.edu.pk.

Anwar Ul Haq (A)

Department of Physics, Govt. Postgraduate College (Boys) Satellite Town, Rawalpindi 46000, Pakistan. anwaar60@yahoo.com.

Muhammad Kamran (M)

Department of Physics, COMSATS University Islamabad (CUI), Islamabad 44000, Pakistan. kamrankhattak@comsats.edu.pk.

Bushra Parveen (B)

Department of Physics, Lahore Garrison University, Lahore 54000, Pakistan. bushra.physics@lgu.edu.pk.

Muhammad Rafiq (M)

Department of Mathematics, COMSATS University Islamabad (CUI) Wah Campus, Wah Cantt 47040, Pakistan. rafiq@ciitwah.edu.pk.

Nazar Abbas Shah (N)

Thin Films Technology (TFT) Research Laboratory, Department of Physics, COMSATS University Islamabad (CUI), Islamabad 44000, Pakistan. waqar00923335167800@gmail.com.

Classifications MeSH