Tailoring grating strip widths for optimizing infrared absorption signals of an adsorbed molecular monolayer.

Metal structures with resonances in the mid-infrared spectral range enable an increased sensitivity for detecting molecular vibrational signals. 1D gold strip gratings have already proven potential in surface-enhanced infrared absorption (SEIRA) experiments, as grating resonances and local electric field enhancement can be spectrally tuned by changing the grating period. Here, we identify the grating strip width as another important design parameter, which is investigated for further optimization of molecular absorption signal enhancement in SEIRA experiments. Previous literature used gratings to increase light absorption in relatively thick polymer layers. Here, we demonstrate the capability of gold strip gratings fabricated on a CaF